121-50-6Relevant articles and documents
A metal-organic framework-templated synthesis of γ-Fe2O3 nanoparticles encapsulated in porous carbon for efficient and chemoselective hydrogenation of nitro compounds
Li, Yang,Zhou, Yu-Xiao,Ma, Xiao,Jiang, Hai-Long
, p. 4199 - 4202 (2016)
The γ-Fe2O3 nanoparticles well dispersed in porous carbon were fabricated via a Fe-based metal-organic framework-templated pyrolysis. The resultant product exhibits excellent catalytic activity, chemoselectivity and magnetic recyclability for the hydrogenation of diverse nitro compounds under mild conditions.
PROCESS FOR SYNTHESIS FIPRONIL
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Paragraph 0060, (2013/03/26)
The present disclosure relates to a process for trifluoromethylsulfinyl pyrazole compound of formula I, from a compound of formula III, wherein, R, R1 and R2 represent a group containing halogen group respectively and R3 represents a perhaloalkyl.
Rapid reduction of heteroaromatic nitro groups using catalytic transfer hydrogenation with microwave heating
Quinn, John F.,Bryant, Cole E.,Golden, Kathryn C.,Gregg, Brian T.
experimental part, p. 786 - 789 (2010/03/24)
A method for the rapid, safe reduction of heteroaromatic and aromatic nitro groups to amines is described using catalytic transfer hydrogenation under microwave heating conditions. Commonly available Pd/C or Pt/C catalyst is extremely effective with 1,4-cyclohexadiene as the hydrogen transfer source. In the case of substrates containing potentially labile aromatic halogens, Pt/C is effective and results in little or no dehalogenation. In general, the reactions are complete within 5 min at 120 °C.
