1213-48-5Relevant articles and documents
Study of the addition of Grignard reagents to 2-aryl-3H-indol-3-ones
Liu, Yahua,McWhorter Jr., William W.
, p. 2618 - 2622 (2007/10/03)
Grignard reagents are added to the carbonyl group of 2-aryl-3H-indol-3-ones to generate 3-alkyl-(or phenyl)-2-aryl-3H-indol-3-ols, which are in turn rearranged to yield 2-alkyl(or phenyl)-2-aryl-1,2-dihydro-3H-indol-3-ones.
3-HYDROPEROXY-3-METHYL-2-PHENYL-3H-INDOLE THERMAL DECOMPOSITION AND CHEMILUMINESCENCE
Nakagawa, Masako,Sato, Masakazu,Watanabe, Yasuji,Hino, Tohru,Hatanaka, Yasumaru,Kanaoka, Yuichi
, p. 503 - 506 (2007/10/02)
Thermolysis of 3-hydroperoxy-3-methyl-2-phenyl-3H-indole 1 in dimethyl sulfoxide showed chemiluminescence and 3-hydroxy-3-methyl-2-phenyl-3H-indole 2 was obtained whereas in methanol 1 was converted to o-benzamidacetophenone.Deoxygenation ocurred to give 2-phenylskatole on the termolysis of 1 in benzene.
THE REARRANGEMENT OF HYDROPEROXYINDOLENINES
McCapra, F.,Long, P. V.
, p. 3009 - 3012 (2007/10/02)
Examination of a series of substituted 3-(hydroxyperoxy)indolenines favours a mechanism for base catalysed decomposition of the dioxetan rather than Criegee type.