122540-27-6 Usage
General Description
The chemical compound "(3Z,5E,8R,9E,11Z,14S,16S,17E,19E,24R)-8,14,16-trihydroxy-24-methyl-1-oxacyclotetracosa-3,5,9,11,17,19-hexaen-2-one" is a complex organic molecule with a cyclohexanone ring and multiple double bonds. It contains three hydroxyl groups at positions 8, 14, and 16, as well as a methyl group at position 24. The compound also has a combination of cis and trans double bond configurations at positions 3, 5, 9, 11, 17, and 19. (3Z,5E,8R,9E,11Z,14S,16S,17E,19E,24R)-8,14,16-trihydroxy-24-methyl-1-oxacyclotetracosa-3,5,9,11,17,19-hexaen-2-one likely has unique properties and potential applications in pharmaceuticals, organic synthesis, or materials science due to its complex structure and multiple functional groups.
Check Digit Verification of cas no
The CAS Registry Mumber 122540-27-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,2,5,4 and 0 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 122540-27:
(8*1)+(7*2)+(6*2)+(5*5)+(4*4)+(3*0)+(2*2)+(1*7)=86
86 % 10 = 6
So 122540-27-6 is a valid CAS Registry Number.
InChI:InChI=1/C24H34O5/c1-20-13-7-3-2-4-8-16-22(26)19-23(27)17-11-5-9-14-21(25)15-10-6-12-18-24(28)29-20/h2,4-6,8-12,14,16,18,20-23,25-27H,3,7,13,15,17,19H2,1H3/b4-2+,10-6+,11-5-,14-9+,16-8+,18-12-/t20-,21+,22-,23+/m1/s1
122540-27-6Relevant articles and documents
Macrolactin W, a new antibacterial macrolide from a marine Bacillus sp.
Mojid Mondol,Kim, Ji Hye,Lee, Hyi-Seung,Lee, Yeon-Ju,Shin, Hee Jae
, p. 3832 - 3835 (2011)
Bioactivity-guided isolation for the new/novel metabolites from the EtOAc extract obtained from the culture broth of a marine Bacillus sp. 09ID194 followed by chromatographic fractionations and subsequently HPLC purifications led to the isolation of two known macrolides, macrolactins A (1) and Q (2), together with a new glycosylated marcrolide, macrolactin W (3). The chemical structures of compounds 1-3 were assigned based on extensive MS and NMR spectral data analysis and literature review. Compound 3 showed potent antibacterial activity against both Gram-positive and Gram-negative pathogenic bacteria.
Total synthesis of macrolactin a with versatile catalytic, enantioselective dienolate aldol addition reactions
Kim, Yuntae,Singer, Robert A.,Carreira, Erick M.
, p. 1261 - 1263 (2007/10/03)
A highly convergent total synthesis of macrolactin A (1) utilizes modern asymmetric catalytic C-C coupling methods. The longest linear sequence in the route is 16 steps with an average yield of 86% per step. This total synthesis is valuable, because 1, which has been shown to possess activity against HIV, is not readily accessible from its natural source, a taxonomically unclassified deep-sea bacterium.
