122885-34-1Relevant articles and documents
Palladium-Catalyzed Synthesis of γ-Allenic α-Amino Acids
Cazes, Bernard,Djahanbini, Dariouche,Gore, Jacques,Genet, Jean-Piere,Gaudin, Jean-Marc
, p. 983 - 985 (2007/10/02)
γ-Allenic α-amino acids can be obtained by a three-step sequence from the phosphates of α-allenic alcohols: i) palladium-catalyzed alkylation of a Schiff base derived from glycine ester by these phosphates, ii) acidic hydrolysis of the imine functionality, and iii) saponification of the resulting amino esters.