125826-60-0

• 

• Basic information

  1. Product Name: tert-butyl (1S,6S)-2-[(Z)-(methoxyimino)methyl]-9-azabicyclo[4.2.1]non-2-ene-9-carboxylate
  2. Synonyms:
  3. CAS NO:125826-60-0
  4. Molecular Formula: C₁₅H₂₄N₂O₃
  5. Molecular Weight: 280.3627
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 125826-60-0.mol
  9. Article Data: 1

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 373.7°C at 760 mmHg
  3. Flash Point: 179.8°C
  4. Appearance: N/A
  5. Density: 1.14g/cm³
  6. Vapor Pressure: 8.81E-06mmHg at 25°C
  7. Refractive Index: 1.541
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: tert-butyl (1S,6S)-2-[(Z)-(methoxyimino)methyl]-9-azabicyclo[4.2.1]non-2-ene-9-carboxylate(CAS DataBase Reference)
  11. NIST Chemistry Reference: tert-butyl (1S,6S)-2-[(Z)-(methoxyimino)methyl]-9-azabicyclo[4.2.1]non-2-ene-9-carboxylate(125826-60-0)
  12. EPA Substance Registry System: tert-butyl (1S,6S)-2-[(Z)-(methoxyimino)methyl]-9-azabicyclo[4.2.1]non-2-ene-9-carboxylate(125826-60-0)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 125826-60-0(Hazardous Substances Data)

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• SDS
• Upstream product
• Downstream Products
• Article

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• 9-Azabicyclo[4.2.1]non-2-ene-9-carboxylicacid, 2-[(methoxyimino)methyl]-, 1,1-dimethylethyl ester, [1R-[1a,2(Z),6a]]- (9CI)

  Cas No: 125826-60-0

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• Hangzhou J&H Chemical Co., Ltd.
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125826-60-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 125826-60-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,5,8,2 and 6 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 125826-60:
(8*1)+(7*2)+(6*5)+(5*8)+(4*2)+(3*6)+(2*6)+(1*0)=130
130 % 10 = 0
So 125826-60-0 is a valid CAS Registry Number.

125826-60-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name	tert-butyl (1S,6S)-5-[(Z)-methoxyiminomethyl]-9-azabicyclo[4.2.1]non-4-ene-9-carboxylate

1.2 Other means of identification

Product number	-
Other names	tert-Butyl (1S,6S)-5-((Z)-methoxyiminomethyl)-9-azabicyclo(4.2.1)non-4-ene-9-carboxylate

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:125826-60-0 SDS

125826-60-0Upstream product

• 593-56-6 N-methoxylamine hydrochloride 
• 125826-59-7 (1R)-9-(tert-butoxycarbonyl)-2-formyl-9-azabicyclo<4.2.1>non-2-ene 
• 125736-12-1 (1R)-9-(tert-butoxycarbonyl)-2-<2-(tert-butyldimethylsiloxy)-acetyl>-9-azabicyclo<4.2.1>non-2-ene 
• 125736-11-0 (1R)-9-(tert-butoxycarbonyl)-2-<1-(tert-butyldimethylsiloxy)-ethenyl>-9-azabicyclo<4.2.1>non-2-ene 
• 125736-18-7 (1R,6R)-2-(Isoxazolidine-2-carbonyl)-9-aza-bicyclo[4.2.1]non-2-ene-9-carboxylic acid tert-butyl ester 
• 125736-13-2 (1R)-9-(tert-butoxycarbonyl)-2-(2-hydroxyacetyl)-9-azabicyclo<4.2.1>non-2-ene 
• 125736-14-3 (1R)-9-(tert-butoxycarbonyl)-2-carboxy-9-azabicyclo<4.2.1>non-2-ene 
• 125736-15-4 (1R)-9-(tert-butoxycarbonyl)-2-(chlorocarbonyl)-9-azabicyclo<4.2.1>non-2-ene 
• 90741-53-0 (1R)-2-acetyl-9-(1-tert-butoxycarbonyl)-9-azobicyclo<4.2.1>-2-nonene 

125826-60-0Downstream Products

125826-60-0Relevant articles and documents

Chirospecific Syntheses of Nitrogen and Side-Chain Modified Anatoxin Analogues. Synthesis of (1R)-Anatoxinal and (1R)-Anatoxinic Acid Derivatives

Howard, Michael H.,Sardina, F. Javier,Rapoport, Henry

, p. 2829 - 2838 (2007/10/02)

A straightforward and good yielding route to side-chain analogues of the potent neurotoxin and neurotransmitter (+)-anatoxin (1) has been developed.Peroxy acid oxidation of the (silyloxy)butadiene 43 derived from readily synthesized, optically pure (1R)-t-BOC-anatoxin (42) affords silyloxy ketone 44.Fluorolysis of 44 followed by oxidative cleavage of the resultant α-hydroxy ketone 45 gives a mixture of α,β-unsaturated acid 46 and ester 41 in 57percent combined yield.Other approaches to these compounds, based on literature precedent, failed. (1R)-t-BOC-anatoxinic acid (46) then serves as educt for the synthesis of a wide variety of anatoxin derivatives with modified side-chain functionality.These analogues, designed to serve as probes of the antagonist binding site of the nicotinic acetylcholine receptor, include alcohol, aldehyde, amide, hydroxamate, and oxime ether functional groups.

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