126222-05-7Relevant articles and documents
Structures and Reactivities of New Dolabellane Diterpenoids from the Caribbean Gorgonian Eunicea laciniata
Shin, Jongheon,Fenical, William
, p. 3392 - 3398 (1991)
Five new diterpenoids of the dolabellane class (3-7) have been isolated from the Caribbean gorgonian Eunicea laciniata Duchassaing and Michelotti.The structures of these metabolites were defined by combined spectra and chemical methods.The conformation and reactivity of the 11-membered ring of the dolabellanes was investigated by 1H NMR nuclear Overhauser enhancement difference spectroscopy (NOEDS) and by selected chemical transformations involving transannular cyclizations.
Total synthesis of the dolabellane marine diterpenoids, claenone, palominol and dolabellatrienone
Miyaoka, Hiroaki,Isaji, Yutaka,Mitome, Hidemichi,Yamada, Yasuji
, p. 61 - 76 (2007/10/03)
The synthesis of marine dolabellane diterpenoids claenone, palominol and dolabellatrienone was conducted from D-mannitol. In each case, formation of the bicyclo[2.2.1]heptane derivative by sequential Michael reaction, preparation of the tetrasubstituted c