129568-35-0Relevant articles and documents
Synthesis of diacetal trioxa-cage compounds via reaction of bicyclo[2.2.1]heptenes and bicyclo[2.2.2]octenes with dimethyldioxirane
Lin, Hui-Chang,Wu, Hsien-Jen
, p. 341 - 350 (2007/10/03)
A new entry for the synthesis of diacetal trioxa-cage compounds via oxirane-induced sequential cyclization reaction of 2,3-bis-endo- diacylbicyclo[2.2.1]-5-heptenes and 2,3-bis-endo-diacylbicyclo[2.2.2]-5- octenes is reported. In the case of bicyclo[2.2.2]octenes, sequential cyclization reaction induced by iodine as electrophile failed. We have also demonstrated that dimethyldioxirane can selectively oxidize hemiacetals to give lactones with the secondary hydroxy group intact. (C) 2000 Elsevier Science Ltd.
Stereospecific total synthesis of (±)pentenomycins by flash vacuum thermolysis of substituted tricyclo[5.2.1.02,6]decenones
Verlaak,Klunder,Zwanenburg
, p. 5463 - 5466 (2007/10/02)
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