13002-10-3Relevant articles and documents
A selective and convenient ruthenium mediated method for the synthesis of mixed acetals and orthoesters
Krompiec, Stanis?aw,Penczek, Robert,Ku?nik, Nikodem,Ma?ecki, Jan Grzegorz,Matlengiewicz, Marek
, p. 137 - 140 (2007)
Addition of alcohols and phenols to O-allyl compounds (allyl ethers and acrolein acetals), catalyzed by [RuCl2(PPh3)3], was examined. Intramolecular addition of an OH group, leading to the formation of cyclic acetals and o
Reactions of trialkylalanes with cyclic acetals and orthoformates in CH2Cl2 and ClCH2CH2Cl as solvents
Gafarova,Dekhtyar',Dekhtyar',Fatykhov,Spirikhin,Vostrikova,Zlotskii,Dokichev
, p. 1003 - 1008 (2007/10/03)
Under mild conditions, trialkylalanes (Et3Al and Bu i3Al) in chlorine-containing solvents (CH 2Cl2 or ClCH2CH2Cl) react with cyclic acetals and orthoformates to form glycol monoethers and dialkylacetals, respectively, in high yields. The 1H NMR spectroscopic data demonstrate that CH2Cl2 or ClCH2CH 2Cl interacts with Bui3Al.