13314-52-8Relevant articles and documents
Beltram, G.,Fehlner, T. P.,Mochida, K.,Kochi, J. K.
, p. 153 - 160 (1980)
Process for the preparation of group IVA and group VIA compounds
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Page 9, (2008/06/13)
Methods of preparing Group IVA and Group VIA organometallic compounds, particularly Group IVA organometallic compounds, are provided. Such manufacturing methods employ an amine and/or phosphine catalyst in a transalkylation step and may be performed in a batch, semi-continuous or continuous manner.
Laser flash photolysis of polygermanes. Generation of germylenes and polygermyl radicals
Mochida, Kunio,Kimijima, Kohichi,Chiba, Hiromi,Wakasa, Masanobu,Hayashi, Hisaharu
, p. 404 - 406 (2008/10/08)
Laser flash photolysis of polygermanes involves both Ge-Ge bond homolysis to give polygermyl radicals and extrusion of germylenes.
Addition 1,4 de divers organo- et organohalogeno-hydrogermanes sur la di-t-butyl-3,5 orthoquinone
Riviere, P.,Castel, A.,Satge, J.,Guyot, D.,Ko, Y. H.
, p. 51 - 60 (2007/10/02)
The thermal 1,4-addition of triorganohydrogermanes R3GeH(R=Et, Ph) with 3,5-di-t-butylorthoquinone leads to their corresponding mono-O-germylated catechols in good yields.Similarly, the organohalohydrogermanes give the 2,2-di-organo- (or 2,2-organohalo)(6,8-di-t-butyl)-4,5-benzo-2-germa-1,3-dioxolanes after dehydrochlorination of transient mono-O-chlorogermylated catechols.Since these reactions are only slightly dependent on solvent and radical initiators, the mechanism probably involves monoelectronic transfer with the formation of a radical anion pair in the first step.The ESR measurements show the transient formation of a paramagnetico-semiquinonic species which supports the proposed mechanism.