13517-10-7Relevant articles and documents
Massey, A, G.,Portal, P. J.
, p. 319 - 319 (1982)
Syntheses and structures of 1,3,5-trihalogeno-1,3,5-triboracyclohexane derivatives
Bayer, Michael J.,Müller, Thomas,L??lein, Wolfgang,Pritzkow, Hans,Siebert, Walter
, p. 782 - 788 (2004)
On heating bis(diiodoboryl)methane (1c) and 1,1-bis(diiodoboryl)alkanes 1i, l (alkane = propane, butane) under reduced pressure elimination of BI 3 takes place and the corresponding 1,3,5-triiodo-1,3,5- triboracyclohexane derivatives 2c; 2i, i′; 2l, l′ are formed. Starting with bis(dichloroboryl)- and bis(dibromoboryl)methane (1a, 1b) only small amounts of the trimerization products (H2C-BCl)3 (2a) and (H2C-BBr)3 (2b) are detectable which can not be separated from 1a,b and by-products. Reaction of 1,3,5-trichloro-2,4,6- trimethyl-1,3,5-triboracyclohexane (2d) with BBr3 provides the corresponding bromo derivative 2e in high yield. An attempt to react 2,4-bis(dichloroboryl)-3-chloro-3-borapentane (4d) with 1,1- bis(trimethylstannyl)-2,2-diphenylethene does not lead to the expected trichloro-triboracyclohexane, but the divinylchloroborane ClB(CH=CPh 2)2 6a, is formed. The compositions of the products follow from analytical data and X-ray structure analyses of 2i, 2c, 2e, and 6a.
Crystal structure of boron triiodide, BI3
Albert, Barbara,Schmitt, Konny
, p. 809 - 810 (2001)
Boron triiodide as a micro-crystalline powder was obtained after sublimation of the reaction product of NaBH4 and iodine. An X-ray powder diagram of the temperature-, air-, and light-sensitive compound was collected at -73°C. According to the results of the Rietveld refinement, the crystal structure of BI3 is isotypic to that of BCl3 (space group P63/m, no. 176, a=699.09(2), c=736.42(3) pm). The B-I bond length was determined to be 211.2(8) pm. Wiley-VCH Verlag GmbH, 2001.
Access to adducts of parent iminoborane isomers, HBNH and NBH2, using frustrated Lewis pair chelation
Ferguson, Michael J.,Frenette, Brandon L.,Oma?a, Alvaro A.,Rivard, Eric,Zhou, Yuqiao
supporting information, p. 10895 - 10898 (2021/10/22)
Adducts of the parent iminoborane isomers, HBNH and NBH2, have been prepared, each stabilized by the frustrated Lewis pair (FLP) chelateiPr2P(C6H4)BCy2(PB).PB{HBNH}was accessedviadehydrohal