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1354-81-0

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1354-81-0 Usage

Description

A tetrahydroisoquinoline alkaloid, brunsvigine has been obtained from Brunsvigia cooperii. It crystallizes from H20 and colourless crystals and has the structure given above which has been confirmed by X-ray analysis.

References

Dry et ai., J. Chern. Soc., 4701 (1958) Inubushietai.,l. Org. Chern., 25, 2153 (1960)

Check Digit Verification of cas no

The CAS Registry Mumber 1354-81-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,3,5 and 4 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1354-81:
(6*1)+(5*3)+(4*5)+(3*4)+(2*8)+(1*1)=70
70 % 10 = 0
So 1354-81-0 is a valid CAS Registry Number.
InChI:InChI=1/C16H17NO4/c18-13-2-10-11-6-17(12(10)4-14(13)19)5-8-1-15-16(3-9(8)11)21-7-20-15/h1-3,11-14,18-19H,4-7H2/t11-,12-,13-,14+/m0/s1

1354-81-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name Brunsvigine

1.2 Other means of identification

Product number -
Other names 3alpha-Pancracine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1354-81-0 SDS

1354-81-0Relevant articles and documents

Bioinspired total synthesis of montanine-type amaryllidaceae alkaloids

Bao, Xu,Cao, Ye-Xing,Chu, Wen-Dao,Qu, Hu,Du, Ji-Yuan,Zhao, Xian-He,Ma, Xiao-Yan,Wang, Cheng-Tao,Fan, Chun-An

, p. 14167 - 14172 (2014/01/06)

Finding a common path: A synthetic strategy inspired by the proposed biogenesis of the montanine-type alkaloids enabled the concise asymmetric synthesis of these compounds in a divergent fashion on the basis of an unprecedented tandem oxidative dearomatization/intramolecular aza-Michael addition as the key step. This bioinspired approach revealed a chemical connection between the cherylline- and montanine-type alkaloids (see scheme). Copyright

Synthesis of aza bicyclic enones via anionic cyclization: Application to the total synthesis of (-)-brunsvigine

Sha, Chin-Kang,Hong, An-Wei,Huang, Chien-Ming

, p. 2177 - 2179 (2007/10/03)

(Matrix presented) A general approach to the synthesis of aza bicyclic enones was developed via a simple two-step annulation involving a Mitsunobu protocol and anionic cyclization. According to this strategy the total synthesis of (-)-brunsvigine was acco

Total synthesis of montanine-type Amarylliidaceae alkaloids, which possess a 5,11-methanomorphanthridine ring system, through cyclization with sodium bis(2-methoxyethoxy)aluminum hydride: The first stereoselective total syntheses of (±)-montanine, (±)-coc

Ishizaki,Hoshino,Iitaka

, p. 7285 - 7295 (2007/10/02)

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