13589-02-1

• 

• Basic information

  1. Product Name: H-PRO-PHE-OH
  2. Synonyms: pro-phecrystalline;L-Pro-L-Phe-OH;N-L-Prolyl-L-phenylalanine;Pro-Phe-OH;PRO-PHE;L-PROLYL-L-PHENYLALANINE;H-PRO-PHE-OH;PROLINE-PHENYLALANINE
  3. CAS NO:13589-02-1
  4. Molecular Formula: C₁₄H₁₈N₂O₃
  5. Molecular Weight: 262.3
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 13589-02-1.mol
  9. Article Data: 6

• Chemical Properties

  1. Melting Point: 250-251 °C
  2. Boiling Point: 531.9 °C at 760 mmHg
  3. Flash Point: 275.5 °C
  4. Appearance: /
  5. Density: 1.228g/cm³
  6. Vapor Pressure: 3.85E-12mmHg at 25°C
  7. Refractive Index: 1.568
  8. Storage Temp.: -15°C
  9. Solubility: Aqueous Acid (slightly)
  10. PKA: 3.40±0.10(Predicted)
  11. CAS DataBase Reference: H-PRO-PHE-OH(CAS DataBase Reference)
  12. NIST Chemistry Reference: H-PRO-PHE-OH(13589-02-1)
  13. EPA Substance Registry System: H-PRO-PHE-OH(13589-02-1)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 13589-02-1(Hazardous Substances Data)

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• SDS
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• Downstream Products
• Article

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13589-02-1 Usage

General Description

The chemical H-PRO-PHE-OH is a dipeptide molecule composed of two amino acids, proline (PRO) and phenylalanine (PHE), linked together by a peptide bond. Proline is a non-essential amino acid that plays a crucial role in protein structure and function, while phenylalanine is an essential amino acid that is important for the production of other molecules in the body. This dipeptide molecule may be used in research or pharmaceutical applications for its potential biological and biochemical activities. It may also have implications in the development of new drug candidates or as a component in nutritional supplements.

Check Digit Verification of cas no

The CAS Registry Mumber 13589-02-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,5,8 and 9 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 13589-02:
(7*1)+(6*3)+(5*5)+(4*8)+(3*9)+(2*0)+(1*2)=111
111 % 10 = 1
So 13589-02-1 is a valid CAS Registry Number.

InChI:InChI=1/C14H18N2O3/c17-13(11-7-4-8-15-11)16-12(14(18)19)9-10-5-2-1-3-6-10/h1-3,5-6,11-12,15H,4,7-9H2,(H,16,17)(H,18,19)/t11-,12-/m0/s1

13589-02-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name	H-PRO-PHE-OH

1.2 Other means of identification

Product number	-
Other names	Pro-Phe-OH

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13589-02-1 SDS

13589-02-1Upstream product

• 35446-32-3 (S)-3-((Ξ)-benzylidene)-hexahydro-pyrrolo[1,2-a]pyrazine-1,4-dione 
• 129398-84-1 (S)-methyl 2-((S)-1-formylpyrrolidine-2-carbonylamino)-3-phenylpropanoate 
• 57177-79-4 (S)-tert-butyl 2-(((S)-1-methoxy-1-oxo-3-phenylpropan-2-yl)carbamoyl)pyrrolidine-1-carboxylate 
• 13200-83-4 (2S)-1-formylpyrrolidine-2-carboxylic acid 
• 1148-11-4 N-Benzyloxycarbonyl-L-proline 
• 23631-72-3 N-carbobenzoxy-L-prolyl-L-phenylalanine methyl ester 
• 147-85-3 L-proline 
• 7524-50-7 methyl (2S)-2-amino-3-phenylpropanoate hydrochloride 
• 15761-39-4 1-(tert-butoxycarbonyl)-L-proline 
• 17350-17-3 (S)-2-[(S)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxamido]-3-phenylpropanoic acid 
• 5654-85-3 (3S,8aS)-3-benzyloctahydropyrrolo[1,2-a]pyrazine-1,4-dione 

13589-02-1Downstream Products

• 56-86-0 L-glutamic acid 
• 147-85-3 L-proline 
• 1352831-51-6 (4S,6aS,11R,11aS)-4-benzyl-N-(2-(6-(dimethylamino)-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)ethyl)-3,6-dioxodecahydro-1H-azirino[1,2-a]pyrrolo[1,2-d][1,4,7]triazonine-11-carboxamide 
• 74258-86-9 alacepril 
• 74259-08-8 1-((S)-3-mercapto-2-methylpropanoyl)-L-prolyl-L-phenylalanine 
• 5654-85-3 (3S,8aS)-3-benzyloctahydropyrrolo[1,2-a]pyrazine-1,4-dione 
• 92278-85-8 Z-Tyr(OBzl)-Pro-Phe-OH 
• 97500-60-2 Tfa-Pro-Phe-OH 

13589-02-1Relevant articles and documents

L-proline-catalyzed asymmetric michael addition of 2-oxindoles to enones: A convenient access to oxindoles with a quaternary stereocenter

Freund, Matthias H.,Tsogoeva, Svetlana B.

, p. 503 - 507 (2011/04/18)

A new organocatalytic approach for 1,4-conjugate addition of 2-oxindoles to α,β-unsaturated ketones using the combination of readily available and nonexpensive l-proline and achiral trans-2,5-dimethylpiperazine as catalytic system is provided. The reaction results in oxindole derivatives with vicinal quaternary and tertiary carbon centers in up to 99% yield and 91% ee. Georg Thieme Verlag Stuttgart.

Chemical Characterization of Diketopiperazines in Beer

Gautschi, Markus,Schmid, Joachim P.,Peppard, Terry L.,Ryan, Thomas P.,Tuorto, Raymond M.,Yang, Xiaogen

, p. 3183 - 3189 (2007/10/03)

Diketopiperazines (DKPs) corresponding to cyclic dipeptides have been detected in a variety of natural products as well as in processed foods, beverages, and food and beverage ingredients. A series of seven proline-based diketopiperazines, namely, cyclo(Ala-Pro), cyclo(Val-Pro), cyclo(Ile-Pro), cyclo(Leu-Pro), cyclo(Met-Pro), cyclo(Phe-Pro), and cyclo(Pro-Pro), has now been identified in beer. A marketplace cross-section of five commercial beers was studied, involving products manufactured in different countries using distinctly different raw materials and brewing styles; maximum concentrations of individual diketopiperazines in various beers ranged from below detection limit to approximately 24 ppm. The flavor characteristics of these compounds were described variously as bitter, mouth coating, drying, astringent, salty, metallic, and grainy when evaluated in water at concentrations ranging from 10 to 50 ppm. However, it is questionable whether or not the diketopiperazines reported here make a significant contribution to either the aroma or taste of most beers.

Anchoring of Amino Acids on Hydroxy Group-Containing Resins and Their Application to Peptide Synthesis Using N-Tritylamino Acid 1-Benzotriazolyl Esters

Barlos, Kleomenis,Gatos, Dimitrios,Kallitsis, John,Papaioannou, Dionysios,Sotiriou, Petros,Schaefer, Wolfram

, p. 1031 - 1036 (2007/10/02)

Trt- and Fmoc-amino acids has been attached to p-alkoxybenzylalcohol resin (ABAR, 1) and diphenylmethanol resin (DPMR, 2) using triphenylphosphan (TPP) and diethyl azodicarboxylate (DEAD) at 0 deg C in tetrahydrofuran.The derived resins have been applied in "solid-phase" peptide synthesis using N-tritylamino acid 1-benzotriazolyl esters 9.

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