13597-12-1Relevant articles and documents
A new 3-D coordination polymer as a precursor for CuI-based thermoelectric composites
Bai, Shi-Qiang,Wong, Ivy Hoi Ka,Zhang, Nan,Lin Ke, Karen,Lin, Ming,Young, David James,Hor, T. S. Andy
, p. 16292 - 16298 (2018)
Two complexes, [Cu6I6(L1)3]n (I) and [Cu4I4(L2)2]n (II) (L1 = 1,4-bis(phenylthio)but-2-yne; L2 = 1,4-bis(phenylthio)butane), as precursors for thermoelectric composite
Preparation of Some Novel Butyl, Butenyl, Butadienyl and Bytynyl Sulfone Electrophiles for Use in Enolate Trapping Studies
Loughlin, Wendy A.,Haynes, Richard K.
, p. 651 - 662 (2007/10/02)
The preparation of some novel four-carbon electrophiles and electrophile intermediates is described.Thus, the chlorobutenyl sulfone (5), the iodobutynyl sulfone (6) and the hitherto unreported chlorobutynyl sulfone (4) were prepared.The novel intermediates, containing a chelating imidazolyl functionality, the N-methylimidazolyl sulfides (13)-(15) were also prepared.However, they polymerized rapidly, thus preventing further synthetic manipulations.The preparation of the α-(trimethylsilyl)butadienyl sulfones (17) and (18) is described and the mode of formation of the intermediate α-trimethylsilyl sulfides (21) and (22) from the trimethylsilylbutenyl sulfide (27) is discussed.