14038-08-5Relevant articles and documents
Reaction of 2,4-Dinitrofluorobenzene with o-Anisidine in Benzene. Further Evidence of the "Dimer" Mechanism
Nudelman, N. Sbarbati,Palleros, Daniel
, p. 1613 - 1617 (1983)
The reaction of 2,4-dinitrofluorobenzene with o-anisidine (B) in benzene exhibits a quadratic dependence of the observed second-order rate coefficient, kA, with , and similar behavior is found in the reaction with p-anisidine, as was previou
Oxidative arylamination of 1,3-dinitrobenzene and 3-nitropyridine under anaerobic conditions: The dual role of the nitroarenes
Gulevskaya, Anna V.,Tyaglivaya, Inna N.,Verbeeck, Stefan,Maes, Bert U.W.,Tkachuk, Anna V.
experimental part, p. 238 - 251 (2011/08/22)
1,3-Dinitrobenzene and 3-nitropyridine react with lithium arylamides under anaerobic conditions to produce N-aryl-2,4-dinitroanilines and N-aryl-5-nitropyridin-2-amines, respectively, in 8-42% yields. ARKAT-USA, Inc.
15N NMR and FTIR studies of 2,4-dinitroanilines and their salts
Gierczyk,Leska,Nowak-Wydra,Schroeder,Wojciechowski,Bartl,Brzezinski
, p. 217 - 225 (2007/10/03)
Twenty-two 2,4-dinitroanilines were synthesised and their pK(a) values were determined. The 2,4-dinitroanilines and their protonated forms were studied by 15N NMR spectroscopy. The relations between the 15N NMR chemical shifts and the pK(a) values of the 2,4-dinitroanilines and their salts were found to be linear. The deprotonation reaction of N-methyl-2,4- dinitroanilines and N-methyl-2,4,6-trinitroaniline by MTBD was successful only for the latter and yielded protonated MTBD molecule and the anion in which the electrons are strongly delocalised. The kinetic parameters of the 2,4-dinitroanilines in reactions with hydroxide ions in mixed solvent DMSO:water (95:5, v/v) were determinated and discussed. (C) 2000 Elsevier Science B.V.
