141573-96-8Relevant articles and documents
Bioinspired Synthesis of a Sedaxane Metabolite Using Catalytic Vanadyl Acetylacetonate and Molecular Oxygen
Tyagi, Sameer,Cook, Christopher D.,Didonato, Dana A.,Key, Jeffrey A.,McKillican, Bruce P.,Eberle, William J.,Carlin, Timothy J.,Hunt, David A.,Marshall, Samantha J.,Bow, Nichola L.
, p. 11941 - 11947 (2015)
A bioinspired synthesis of the sedaxane metabolite 2 from intermediate 3 using catalytic VO(acac)2 and O2 is described. Intermediate 3 was synthesized starting from 2-bromostyrene in four steps. The inner cyclopropyl ring of 3 was assembled with trans geometry using a highly diastereoselective Nishiyama cyclopropanation, and the outer hydroxycyclopropyl ring was installed using the Kulinkovich cyclopropanation. Additionally, conversion of 3 into 2 was demonstrated in in vitro microbial culture experiments consisting of bacteria and fungi.
METHOD FOR PRODUCING OPTICALLY ACTIVE 1,1,3-TRIMETHYL-4-AMINOINDANE
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Paragraph 0054, (2022/01/24)
The purpose of the present invention is to provide a novel method for producing optically active 1,1,3-trimethyl-4-aminoindane by means of a preferential crystallization method using an achiral acid and without using an optically active acid. The present
Novel pyrazole amide compound and preparation thereof, and application of novel pyrazole amide compound in prevention and treatment of plant pathogenic diseases and pest killing
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Paragraph 0033; 0038-0039, (2021/06/26)
The invention relates to a novel pyrazole amide compound I and a preparation method thereof and application of the novel pyrazole amide compound I in prevention and treatment of plant pathogenic disease and pest killing. The novel pyrazole amide compound
Azo-incorporating Increases Inhibitory Activity of Succinate Dehydrogenase
Cheng, Jiagao,Fu, Wen,Hu, Xinyue,Li, Zhong,Shao, Xusheng,Sun, Xujuan,Xu, Zhiping,Ye, Yonghao,Yuan, Qinglong,Zhang, Yang
, p. 13448 - 13459 (2021/11/23)
Diversity of pesticide discovery provided a solution to resistance. Here, we presented a strategy of azo-incorporating to promote the diverse developments of fungicide. A series of novel fungicides were synthesized by incorporating azobenzene derivatives
