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14273-85-9

14273-85-9

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14273-85-9 Usage

Uses

Methyl 4-iodobutyrate may be used as reagent in the synthesis of 4-[formyl-5-(methoxymethyl)-1H-pyrrol-1-yl] butanoic acid. It has been used in the synthesis of a range of stable S-adenosylmethionine (SAM) mimetics. Their ability to promote the binding of the E. coli methionine repressor (MetJ) to its operator DNA has been investigated.

General Description

Methyl 4-iodobutyrate can be synthesized from methyl-4-chlorobutyrate and sodium iodide.

Check Digit Verification of cas no

The CAS Registry Mumber 14273-85-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,2,7 and 3 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 14273-85:
(7*1)+(6*4)+(5*2)+(4*7)+(3*3)+(2*8)+(1*5)=99
99 % 10 = 9
So 14273-85-9 is a valid CAS Registry Number.
InChI:InChI=1/C5H9IO2/c1-8-5(7)3-2-4-6/h2-4H2,1H3

14273-85-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name Methyl 4-iodobutyrate

1.2 Other means of identification

Product number -
Other names methyl 4-iodobutanoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14273-85-9 SDS

14273-85-9Relevant articles and documents

Synthetic Methods and Reactions; 107. Preparation of ω-Haloalkylcarboxylic Acids and Esters or Related Compounds from Lactones and Boron Trihalides

Olah, George A.,Karpeles, Richard,Narang, Subhash C.

, p. 963 - 965 (1982)

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Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes

Bai, Songlin,Gao, Yadong,Jiang, Chao,Liu, Xiaolei,Qi, Xiangbing,Wang, Jing,Wu, Qingcui,Yang, Chao

supporting information, p. 675 - 688 (2020/03/11)

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Phosphorothioic acids and related compounds as surrogates for H 2S-synthesis of chiral tetrahydrothiophenes

Robertson, Forest J.,Wu, Jimmy

supporting information; experimental part, p. 2775 - 2780 (2012/03/22)

The convenient preparation of chiral tetrahydrothiophenes (THTs) in high enantiopurity via phosphorothioic acids and related compounds is reported. We consider these to be safer alternatives to the use of H2S which is a highly toxic gas. Each o

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