14323-43-4Relevant articles and documents
Fabrication of Pd-Fe nanowires with a high aspect ratio by AAO template-assisted electrodeposition
Taaltin, Nevin,?ztürk, Sadullah,Kilin, Necmettin,Yüzer, Hayrettin,?ztürk, Zafer Ziya
, p. 3894 - 3898 (2011/04/22)
In this study, vertically oriented Pd0.86Fe0.14 nanowires have been fabricated using an anodized aluminum oxide (AAO) template by direct voltage electrodeposition at room temperature. AAO template-assisted electrodeposition of Pd-Fe was carried out in Pd(NH3) 2Cl2:FeSO4·7H2O solution. The AAO template and the Pd0.86Fe0.14 nanowires were characterized by scanning electron microscopy (SEM), energy dispersive X-ray (EDX) methods and X-ray diffraction (XRD). It was observed that the Pd 0.86Fe0.14 nanowires were approximately 65 nm in diameter and 10 μm in length with an aspect ratio of 153 in a relatively large area of about 4 cm2. The nucleation rate and the number of atoms in the critical nucleus are determined from the analysis of current transients.
Synthesis, crystal structure, and thermal properties of [Pd(NH 3)4][AuCl4]2
Plyusnin,Baidina,Shubin,Korenev
, p. 371 - 377 (2008/10/09)
The double complex salt [Pd(NH3)4][AuCl 4]2 was synthesized and studied by X-ray diffraction: a = 7.5234(6) ?, b = 7.7909(5) ?, c = 8.0247(6) ?, α = 108.483(2)°, β = 106.497(2)°, γ = 99.972(3)°, V = 409.43(5) ?3, space group P1?, Z = 1, ρ calod = 3.456 g/cm3, R = 0.0267. The compound was characterized by powder X-ray diffraction, thermal analysis, and IR and Raman spectroscopy. The metal products of thermolysis of the complex were studied by powder X-ray diffraction. Nauka/Interperiodica 2007.
The synthesis and properties of the bicomplex compounds of ruthenium and palladium
Kokunova,Kravchenko
, p. 643 - 646 (2008/10/08)
The ruthenium and palladium bicomplex compounds of compositions [Pd(NH3)4[RuNOCl5], [Pd(NH3)4][RuNO(NO2)4OH], and [RuNO(NH3)4OH][PdCl4], in which the RuNO(+3) fragment is placed either in the anionic or in the cationic part of the compound, are synthesized. The composition and structure of the compounds and products of their thermal decomposition are established from derivatography; thermal, elemental, and X-ray powder analyses; IR spectroscopy; and Raman scattering data. It is found that, on heating [Pd(NH3)4][RuNOCl5], the NH3 molecules and Cl- ions are exchanged between the cationic and anionic moieties of the complex to form trans-[Pd(NH3)2Cl2] and trans-[RuNO(NH3)2Cl3].
