144175-17-7Relevant articles and documents
New carbon-carbon bond forming reactions of cyclic sulfate esters and cyclic sulfamidates
Pound, Melanie K,Davies, Darren L,Pilkington, Melanie,De Pina Vaz Sousa, Maria M,Wallis, John D
, p. 1915 - 1918 (2002)
Carbon-carbon bonding forming reactions of two cyclic sulfate esters and a cyclic sulfamidate are reported, the former with lithium dianions to give substituted tetrahydrofuran derivatives with displacement of sulfate, and the latter undergoes ring-openin
Reaction of Dianions of Acyclic β-Enamino Ketones with Electrophiles. Part 2. Oxiranes: Synthesis of γ'- and ε-Hydroxy-β-enamino Ketones and of α-Tetrahydrofurylidene Ketones.
Bartoli, Giuseppe,Bosco, Marcella,Cimarelli, Cristina,Dalpozzo, Renato,Palmieri, Gianni
, p. 2095 - 2100 (2007/10/02)
β-Monoalkylamino-α,β-unsaturated ketones can be regioselectively dimetallated either at the α'- or in the γ-positions.The reaction of the resulting dianions with oxiranes proceeds in good to high yields affording the corresponding hydroxyalkyl derivatives