144370-33-2Relevant articles and documents
Highly functionalized donor-acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids
Goldberg, Alexander F.G.,Craig, Robert A.,O'Connor, Nicholas R.,Stoltz, Brian M.
supporting information, p. 2983 - 2990 (2015/05/27)
Abstract A series of highly substituted vinylcyclopropanes were prepared and examined as reaction partners in a palladium-catalyzed (3+2) cycloaddition with nitrostyrenes. Described herein are our efforts to synthesize an elusive 1,1-divinylcyclopropane by several distinct approaches, and to apply surrogates of this fragment toward the synthesis of the Melodinus alkaloids.
Auto-tandem catalysis: Facile synthesis of substituted alkylidenecyclohexanones by domino (4+2) cycloaddition-elimination reaction
Takasu, Kiyosei,Tanaka, Toru,Azuma, Takumi,Takemoto, Yoshiji
scheme or table, p. 8246 - 8248 (2010/12/20)
A catalytic domino reaction producing substituted 2-alkylidenecyclohexanone from 3-oxymethyl-2-siloxy-1,3-butadienes, which can be prepared from Baylis-Hillman adducts, and α,β-unsaturated ketones is described. The process involves two mechanistically dis
Stereoselective synthesis of methyl 7-dihydro-trioxacarcinoside B
Koenig, Christian M.,Harms, Klaus,Koert, Ulrich
, p. 4777 - 4779 (2008/03/15)
(Chemical Equation Presented) A stereoselective synthesis of 7-dihydro-triocacarcinose B, a branched octose from the quinocyclines, has been achieved. The biocatalytic resolution of a Baylis-Hillman adduct and a subsequent ring-closing metathesis were use