1460-97-5

• 

• Basic information

  1. Product Name: [1R,(-)]-1,2,3,4,4aα,5,6,8aβ-Octahydro-7-methyl-4-methylene-1-isopropylnaphthalene
  2. Synonyms: 1b,6a,7bH-Cadina-4,10(15)-diene (8CI); Naphthalene, 1,2,3,4,4a,5,6,8a-octahydro-7-methyl-4-methylene-1-(1-methylethyl)-,[1R-(1a,4ab,8aa)]-; (-)-g-Cadinene;g-Cadinene, (-)-
  3. CAS NO:1460-97-5
  4. Molecular Formula: C15H24
  5. Molecular Weight: 204.35106
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 1460-97-5.mol
  9. Article Data: 3

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 272.1°Cat760mmHg
  3. Flash Point: 106.8°C
  4. Appearance: /
  5. Density: 0.89g/cm³
  6. Vapor Pressure: 0.0103mmHg at 25°C
  7. Refractive Index: 1.492
  8. Storage Temp.: N/A
  9. Solubility: N/A
  10. CAS DataBase Reference: [1R,(-)]-1,2,3,4,4aα,5,6,8aβ-Octahydro-7-methyl-4-methylene-1-isopropylnaphthalene(CAS DataBase Reference)
  11. NIST Chemistry Reference: [1R,(-)]-1,2,3,4,4aα,5,6,8aβ-Octahydro-7-methyl-4-methylene-1-isopropylnaphthalene(1460-97-5)
  12. EPA Substance Registry System: [1R,(-)]-1,2,3,4,4aα,5,6,8aβ-Octahydro-7-methyl-4-methylene-1-isopropylnaphthalene(1460-97-5)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 1460-97-5(Hazardous Substances Data)

• Suppliers
• Usage
• SDS
• Upstream product
• Downstream Products
• Article

1460-97-5 Suppliers

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• gamma-cadinene

  Cas No: 1460-97-5

• USD $ 3.0-3.0 / Kilogram

• 1 Kilogram

• 1-100 Metric Ton/Month

• Dayang Chem (Hangzhou) Co.,Ltd.
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• 7-methyl-4-methylidene-1-propan-2-yl-2,3,4a,5,6,8a-hexahydro-1H-naphthalene

  Cas No: 1460-97-5

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• BOC Sciences
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• [1R,(-)]-1,2,3,4,4aα,5,6,8aβ-Octahydro-7-methyl-4-methylene-1-isopropylnaphthalene

  Cas No: 1460-97-5

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• ZHEJIANG JIUZHOU CHEM CO.,LTD
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• [1R,(-)]-1,2,3,4,4aα,5,6,8aβ-Octahydro-7-methyl-4-methylene-1-isopropylnaphthalene

  Cas No: 1460-97-5

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• Shanghai Run-Biotech Co., Ltd.
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1460-97-5 Usage

Uses

(-)-γ-Cadinene is a sesquiterpene and can be isolated from A. terreus. It is an antioxidant agent.

Definition

ChEBI: A member of the cadinene family of sesquiterpenes in which the isopropyl group is cis to the hydrogen at the adjacent bridgehead carbon (the 1R,4aS,8aS enantiomer).

Check Digit Verification of cas no

The CAS Registry Mumber 1460-97-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,4,6 and 0 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1460-97:
(6*1)+(5*4)+(4*6)+(3*0)+(2*9)+(1*7)=75
75 % 10 = 5
So 1460-97-5 is a valid CAS Registry Number.

InChI:InChI=1/C15H24/c1-10(2)13-8-6-12(4)14-7-5-11(3)9-15(13)14/h9-10,13-15H,4-8H2,1-3H3

1460-97-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name	(?)-γ-cadinene

1.2 Other means of identification

Product number	-
Other names	-

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1460-97-5 SDS

1460-97-5Upstream product

• 3484-48-8 Kadin-4, 10(15)-dien-3α-ol 
• 64340-25-6 Khusol-tosylat 
• 76192-48-8 [1-²H]farnesal 
• 91411-05-1 (S)-<1-2H>(E,E)-3,7,11-trimethyl-2,6,10-dodecatrien-1-ol 
• 115826-59-0 (1S)-<1-²H>farnesyl diphosphate 
• 483-76-1 delta-cadinene 
• 481-34-5 (+)-α-cadinol 
• 113888-84-9 C₂₉H₃₆O₇S₂ 
• 113888-83-8 C₁₅H₂₄O₃ 
• 113888-82-7 vetidiol 

1460-97-5Downstream Products

1460-97-5Relevant articles and documents

Lessons from 1,3-Hydride Shifts in Sesquiterpene Cyclizations

Rinkel, Jan,Rabe, Patrick,Garbeva, Paolina,Dickschat, Jeroen S.

, p. 13593 - 13596 (2016)

Stereospecifically labelled precursors were subjected to conversion by seven bacterial sesquiterpene cyclases to investigate the stereochemistry of their initial 1,10-cyclisation-1,3-hydride shift cascades. Enzymes with products of known absolute configuration showed a coherent stereochemical course, except for (?)-α-amorphene synthase, for which the obtained results are better explained by an initial 1,6-cyclisation. The link between the absolute configuration of the product and the stereochemical course of the 1,3-hydride shifts enabled assignment of the absolute configurations of three enzyme products, which were confirmed independently through the absolute configuration of the common byproduct germacrene D-4-ol.

-

Kalsi,P.S. et al.

, p. 1073 - 1078 (1963)

-

Stereostructure of vetidiol, a new antipodal sesquiterpene diol from vetiver oil; A novel role of biological activity to predict the position and stereochemistry of one of the hydroxyl group

Kalsi,Talwar

, p. 2985 - 2988 (2007/10/02)

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