14606-42-9 Usage
Description
TRIPHENYLSILANETHIOL, also known as triphenylsilyl thiol, is an organic compound characterized by its triphenylsilyl group and thiol functional group. It is a versatile reagent in organic synthesis and possesses unique chemical properties that make it valuable in various applications.
Uses
Used in Organic Synthesis:
TRIPHENYLSILANETHIOL is used as an organic building block for carboxyl activation via silylthioesterification. This process is crucial in the synthesis of various complex organic molecules, as it allows for the selective activation and modification of carboxyl groups.
Used in the Preparation of Tetraphenylporphyrinate Manganese(III) Siloxides:
TRIPHENYLSILANETHIOL is also utilized in the synthesis of tetraphenylporphyrinate manganese(III) siloxides, which are important compounds in the field of materials science. These siloxides exhibit unique optical, electronic, and magnetic properties, making them promising candidates for applications in optoelectronics, sensors, and other advanced technologies.
Check Digit Verification of cas no
The CAS Registry Mumber 14606-42-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,6,0 and 6 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 14606-42:
(7*1)+(6*4)+(5*6)+(4*0)+(3*6)+(2*4)+(1*2)=89
89 % 10 = 9
So 14606-42-9 is a valid CAS Registry Number.
InChI:InChI=1/C18H16SSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
14606-42-9Relevant articles and documents
Preparation of silanethiols by reaction of silanes with triphenylphosphine sulfide and with alkanethiols
Cai, Yudong,Roberts, Brian P.
, p. 4581 - 4584 (2001)
Silanes react with triphenylphosphine sulfide by a radical-chain mechanism to give the corresponding silanethiols in good yield. Silanethiols are similarly formed when silanes react with tert-dodecanethiol. Enantiomerically pure (S)-ButMePhSiH gave racemic silanethiol with Ph3P=S, but with tert-dodecanethiol silanethiol with an ee up to 60% has been obtained, although in low chemical yield.
