15107-41-2Relevant articles and documents
Nickel-Catalyzed Regiodivergent Reductive Hydroarylation of Styrenes
Xue, Yuhang,Chen, Jian,Song, Peihong,He, Yuli,Zhu, Shaolin
supporting information, p. 1647 - 1651 (2021/07/02)
We report a ligand-controlled nickel-catalyzed reductive hydroarylation of styrenes with predictable and controllable regioselectivity. With a diamine ligand, the reaction produces selective linear hydroarylation products. Alternatively, with a chiral PyrOx ligand, branch-selective enantioenriched 1,1-diarylalkane products are obtained. Preliminary mechanistic results are consistent with a reductive Heck process.
Thermal Rearrangement of Sulfamoyl Azides: Reactivity and Mechanistic Study
Zou, Xiaodong,Zou, Jiaqi,Yang, Lizheng,Li, Guigen,Lu, Hongjian
, p. 4677 - 4688 (2017/05/12)
The rearrangement of sulfamoyl azides under thermal conditions to form a C-C bond while breaking two C-N bonds is reported. Mechanistic study shows that this reaction goes through a Curtius-type rearrangement to form a 1,1-diazene, then which rearranges possibly through both a concerted rearrangement process and a stepwise radical process. This rearrangement could be used in the synthesis of complex biologically active molecules, such as sterols, and piperine derivatives.
