151797-32-9

• 

• Basic information

  1. Product Name: 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL
  2. Synonyms: 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL;3,4-di-O-acetyl-6-O-(tert-butyldiphenyl-silyl)-D-
  3. CAS NO:151797-32-9
  4. Molecular Formula: C₂₆H₃₂O₆Si
  5. Molecular Weight: 502.63
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 151797-32-9.mol
  9. Article Data: 4

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 509.6±50.0 °C(Predicted)
  3. Flash Point: >230 °F
  4. Appearance: /
  5. Density: 1.14±0.1 g/cm3(Predicted)
  6. Refractive Index: n20/D 1.456(lit.)
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL(CAS DataBase Reference)
  10. NIST Chemistry Reference: 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL(151797-32-9)
  11. EPA Substance Registry System: 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL(151797-32-9)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany: 3
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 151797-32-9(Hazardous Substances Data)

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• SDS
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• 3,4-DI-O-ACETYL-6-O-(TERT-BUTYLDIPHENYLSILYL)-D-GLUCAL

  Cas No: 151797-32-9

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• Hangzhou Fandachem Co.,Ltd
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• 3,4-Di-O-acetyl-6-O-tert-butyldiphenylsilyl-D-glucal

  Cas No: 151797-32-9

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• 1 Gram

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151797-32-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 151797-32-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,1,7,9 and 7 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 151797-32:
(8*1)+(7*5)+(6*1)+(5*7)+(4*9)+(3*7)+(2*3)+(1*2)=149
149 % 10 = 9
So 151797-32-9 is a valid CAS Registry Number.

151797-32-9 Well-known Company Product Price

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• Aldrich

• (MAR000010)  3,4-Di-O-acetyl-6-O-(tert-butyldiphenylsilyl)-D-glucal  Aldrich^CPR

• 151797-32-9

• MAR000010-1G

• 0.00CNY

• Detail

151797-32-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name	[(2R,3R,4R,5R)-4-acetyloxy-1-[tert-butyl(diphenyl)silyl]oxy-2,5-dihydroxy-6-oxohexan-3-yl] acetate

1.2 Other means of identification

Product number	-
Other names	3,4-di-O-acetyl-6-O-TBDPS-D-glucal

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:151797-32-9 SDS

151797-32-9Upstream product

• 2873-29-2 D-glucal triacetate 
• 13265-84-4 D-glucal 
• 224778-57-8 1,2,3,4-tetra-O-acetyl-6-O-tert-butyldiphenylsilyl-α/β-D-glucopyranose 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 180072-36-0 2,3,4-tri-O-acetyl-6-O-[(1,1-dimethylethyl)diphenylsilyl]-α-D-glucopyranosyl bromide 
• 87316-22-1 (2R,3S,4R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diol 
• 108-24-7 acetic anhydride 
• 65620-65-7 1,2,3,4-tetra-O-acetyl-D-glucopyranose 

151797-32-9Downstream Products

• 1554363-83-5 (2R,3R,4S)-5-bromo-2-((tert-butyldiphenylsilyloxy)methyl)-3,4-dihydro-2H-pyran-3,4-diyldiacetate 
• 1554363-77-7 (2R,3R,4S)-2-((tert-butyldiphenylsilyloxy)methyl)-5-iodo-3,4-dihydro-2H-pyran-3,4-diyldiacetate 
• 1354577-33-5 (2R,3S)-acetic acid 2-(tert-butyldiphenylsilanyloxymethyl)-3,4-dihydro-2H-pyran-3-yl ester 

151797-32-9Relevant articles and documents

2-nitroglycal and efficient synthesis method thereof

-

, (2021/08/06)

The invention discloses an efficient synthesis method of 2-nitroglycal, and belongs to the technical field of synthesis of sugar. The structure of the 2-nitroglycal is shown in the specification. Secondly, the invention also provides a preparation method of the 2-nitro saccharide alkene, and the preparation method provided by the invention can be used for efficiently preparing the 2-nitroglycal through one-step synthesis.

Variously substituted glycals are readily prepared from glycosyl bromides using (Cp2TiCl)2

Spencer, Roxanne P.,Schwartz, Jeffrey

, p. 4357 - 4360 (2007/10/03)

Glycosyl halides, variously substituted with ether, acetal, or ester protecting groups, were converted to the corresponding glycals in high yield by reaction with (Cp2TiCl)2. A glycosyl chloride was less reactive than the analogous bromide.

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