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152090-39-6

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152090-39-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 152090-39-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,2,0,9 and 0 respectively; the second part has 2 digits, 3 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 152090-39:
(8*1)+(7*5)+(6*2)+(5*0)+(4*9)+(3*0)+(2*3)+(1*9)=106
106 % 10 = 6
So 152090-39-6 is a valid CAS Registry Number.

152090-39-6Downstream Products

152090-39-6Relevant articles and documents

Neighboring Group Participation in Lewis Acid-Promoted and Annulations. The Stereocontrolled Synthesis of Tricyclic Ethers

Molander, Gary A.,Cameron, Kimberly O.

, p. 5931 - 5943 (2007/10/02)

A variety of 1,4- and 1,5-keto aldehydes derived from cycloalkanes are coupled with the bis(trimethylsilyl) enol ether of methyl acetoacetate in the presence of either TMSOTf or TrSbCl6 to generate tricyclic ethers.The reactions proceed with excellent regiochemical control by a mechanism involving neighboring group participation.This mechanism involves initial formation of a bicyclic oxocarbenium ion intermediate from the keto aldehyde substrates.The geometries of selected bicyclic intermediates have been optimized using the AM1 method allowing successful prediction of the stereochemical outcomes in the cyclization in most cases.Epimerization of α-chiral keto aldehyde substrates does not appear to occur in these Lewis acid-promoted annulation reactions.

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