154965-03-4Relevant articles and documents
Synthesis and characterization of some monomeric and dimeric silver(I)-phosphine complexes with N-donor bridging ligands
Sarkhel, Prashanta,Bhattacharjee, Suchandra,Sarkhel, Sejuti,Chakraborty, Surajit
, p. 1154 - 1157 (2013/01/14)
The monomeric complexes [Ag(PPh3)2]X (X = ClO 4 - or NO3) was synthesized by a metathesis reaction of [Ag2(PPh3)4(μ-SO4)] with BaX2 (where X = ClO4 - or NO3 -) in ethanol. The reactivity of [Ag(PPh3)2]X (where X = ClO4 - or NO3 -) with some potential N-donor bridging ligands viz. 4,4 bipyridine and pyrazine yielded dimeric complexes of the type [Ag2(PPh3) 4(μ-L-L)]X2 (where L-L = 4,4-bipyridine or pyrazine, and X = ClO4 - or NO3 -). All these complexes were characterized by infrared spectroscopy, conductivity measurements, cyclic voltammetry, 1H NMR, and electronic spectroscopy.
SYNTHESIS AND REACTIVITY OF MONO- AND HETERO-NUCLEAR RHODIUM(I) OR IRIDIUM(I) COMPLEXES WITH 2-(2'-PYRIDYL)BENZIMIDAZOLE
Uson, Rafael,Oro, Luis A.,Cabeza, Javier A.
, p. 105 - 116 (2007/10/02)
Rhodium(I) and iridium(I) complexes of the formulae M(PyBzIm)(diolefin), ClO4, (diolefin)M(μ-PyBzIm)AuCl, ClO4 (L = PPh3 or P(OMe)3), ClO4 and 2>ClO4 (diolefin = COD or NBD) are described.The related carbonyl derivatives M(PyBzIm)(CO)Y, ClO4 (Y = CO or PPh3), (CO)2M(μ-PyBzIm)AuCl, ClO4, 2>ClO4 and 2>ClO4 have been obtained by reaction of diolefin derivatives with carbon monoxide and triphenylphosphine.
