156540-92-0Relevant articles and documents
Asymmetric isomerization of ω-hydroxy-α,β-unsaturated thioesters into β-mercaptolactones by a bifunctional aminothiourea catalyst
Fukata, Yukihiro,Okamura, Takaaki,Asano, Keisuke,Matsubara, Seijiro
supporting information, p. 2184 - 2187 (2014/05/06)
We present a novel methodology for the asymmetric synthesis of β-mercaptolactones via isomerization of ω-hydroxy-α,β- unsaturated thioesters by means of a bifunctional aminothiourea catalyst. The catalyst interacts with the substrate through the cooperati