156697-63-1

• 

• Basic information

  1. Product Name: Aziridine, 2-(bromomethyl)-1-[(4-methylphenyl)methyl]-
  2. Synonyms:
  3. CAS NO:156697-63-1
  4. Molecular Formula: C11H14BrN
  5. Molecular Weight: 240.143
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 156697-63-1.mol
  9. Article Data: 2

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: N/A
  3. Flash Point: N/A
  4. Appearance: N/A
  5. Density: N/A
  6. Refractive Index: N/A
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: Aziridine, 2-(bromomethyl)-1-[(4-methylphenyl)methyl]-(CAS DataBase Reference)
  10. NIST Chemistry Reference: Aziridine, 2-(bromomethyl)-1-[(4-methylphenyl)methyl]-(156697-63-1)
  11. EPA Substance Registry System: Aziridine, 2-(bromomethyl)-1-[(4-methylphenyl)methyl]-(156697-63-1)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 156697-63-1(Hazardous Substances Data)

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• Usage
• SDS
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• Downstream Products
• Article

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• Aziridine, 2-(bromomethyl)-1-[(4-methylphenyl)methyl]-

  Cas No: 156697-63-1

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156697-63-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 156697-63-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,6,6,9 and 7 respectively; the second part has 2 digits, 6 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 156697-63:
(8*1)+(7*5)+(6*6)+(5*6)+(4*9)+(3*7)+(2*6)+(1*3)=181
181 % 10 = 1
So 156697-63-1 is a valid CAS Registry Number.

156697-63-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name	2-(bromomethyl)-1-[(4-methylphenyl)methyl]aziridine

1.2 Other means of identification

Product number	-
Other names	2-(bromomethyl)-1-<(4-methylphenyl)methyl>aziridine

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:156697-63-1 SDS

156697-63-1Upstream product

• 156697-64-2 (E)-N-(4-methylbenzylidene)prop-2-en-1-amine 
• 104-87-0 4-methyl-benzaldehyde 
• 80975-83-3 N-(4-methylbenzylidene)prop-2-en-1-amine 
• 188818-02-2 N-(4-methylbenzylidene)-2,3-dibromopropylamine 
• 156697-67-5 (2,3-Dibromo-propyl)-[1-p-tolyl-meth-(E)-ylidene]-amine 

156697-63-1Downstream Products

• 86926-54-7 N-(4-methylbenzyl)prop-2-en-1-amine 
• 952024-07-6 2-(2-cyanoethyl)-1-[(4-methylphenyl)methyl]aziridine 

156697-63-1Relevant articles and documents

A new synthesis of 2-methyleneaziridines

De Kimpe, Norbert,De Smaele, Dirk,Sakonyi, Zsolt

, p. 2448 - 2452 (2007/10/03)

A new synthetic route leading to 2-methyleneaziridines has been developed by base-induced 1,2-dehydrobromination of 2-(bromomethyl)aziridines. Several base-solvent pairs did not lead to 2-methyleneaziridines. Only potassium tert-butoxide in tetrahydrofuran afforded 2-methyleneaziridines in competition with the substitution products, i.e. 2-(tert-butoxymethyl)aziridines. Various attempted functionalizations of 1-(arylmethyl)-2-methyleneaziridines failed, but they proved to be excellent substrates for the synthesis of β-lactam derivatives, i.e. 1-(arylmethyl)-2-iminoazetidines, through ring expansion with azides carrying electron-withdrawing substituents.

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