1569-44-4Relevant articles and documents
Predicting and optimizing asymmetric catalyst performance using the principles of experimental design and steric parameters
Harper, Kaid C.,Sigman, Matthew S.
, p. 2179 - 2183 (2011)
Using a modular amino acid based chiral ligand motif, a library of ligands was synthesized systematically varying the substituents at two positions. The effects of these changes on ligand structure were probed in the enantioselective allylation of benzald
Hydroalumination of terminal β-acetylene alcohols with lithium aluminum hydride
Garibyan,Makaryan,Ogannisyan,Chobanyan
, p. 267 - 272 (2016/04/20)
Hydrogenation of terminal β-acetylene alcohols with lithium aluminum hydride in THF has afforded homoallylic alcohols. Decomposition of the intermediate organoaluminum complex with deuterated water, iodine, or pyridinium dibromide has evidenced about the non-regioselective hydride attack at the triple bond.
Allylation of carbonyl compounds mediated by Aluminum/Fluoride salts in water
Yuan, Shizhen,Liu, Jin,Xu, Ling,Zhu, Shaofeng
experimental part, p. 578 - 582 (2010/10/04)
A novel mediator (Al/KF) has been developed and employed in the Barbier-type alkylations of various aldehydes and ketones with alkyl halide in water. The carbonyl compounds could be effectively converted into corresponding homoallylic alcohol in good yiel