16165-72-3Relevant articles and documents
High yield synthesis of some phosphonic acid derivatives as surface tethers for energy harvesting technologies
Mungalimane, Amshumali
, p. 143 - 148 (2014)
Efficient synthesis of novel 6-(2-bromo-2-methyl propanoyloxy)hexyl phosphonic acid, dodecane di-phosphonic acid, 6-(thiophene-3-carbonyloxy)hexyl phosphonic acid, octadecyl phosphonic acid and such other derivatives are reported here. These derivatives have a potential application as tethers to nanoparticle surfaces that can promote efficient electron transfer process in solar energy conversion.
Synthesis and structural study of long-chain hydrocarbon alkylphosphonic acids
Gaboyard,Hervaud,Boutevin
, p. 877 - 891 (2007/10/03)
Long-chain dialkyl alkylphosphonates were synthesized by radical addition of dialkyl hydrogenphosphonates onto alkenes in presence of di(t-butyl) peroxide. This synthetic route leads to high yields between 94 and 97%. We performed chemical modifications of these phosphonates in order to obtain acidic derivatives. The structure of these compounds was characterized by NMR analyses and mass spectroscopy. We also studied their thermal behaviour and various crystalline phases were put in evidence by differential scanning calorimetry and optical microscopy. The thermal stability of these compounds was compared by thermogravimetric analyses.
