163353-67-1Relevant articles and documents
Reaction of chlorosulfonyl isocyanate with fluorosubstituted alkenes: Evidence of a concerted pathway
Shellhamer, Dale F.,Davenport, Kevyn J.,Hassler, Danielle M.,Hickle, Kelli R.,Thorpe, Jacob J.,Vandenbroek, David J.,Heasley, Victor L.,Boatz, Jerry A.,Reingold, Arnold L.,Moore, Curtis E.
experimental part, p. 7913 - 7916 (2011/02/25)
Concerted reactions are indicated for the electrophilic addition of chlorosulfonyl isocyanate with monofluoroalkenes. A vinyl fluorine atom on an alkene raises the energy of a stepwise transition state more than the energy of the competing concerted pathw