16725-53-4Relevant articles and documents
SYNTHESIS OF ONE OF THE SEX PHEROMONES OF Heliothis levre - cis-TETRADEC-9-EN-1-OL ACETATE
Dzhumakulov, T.,Yuldashev, A. M.,Abduvakhabov, A. A.
, p. 516 - 517 (1982)
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Polymer-anchored Organosilyl Protecting Group in Organic Synthesis
Chan, Tak-Hang,Huang, Wen-Qiang
, p. 909 - 911 (1985)
Polymer-anchored dimethyl- and diphenyl-chlorosilanes (1a) and (1b) have been prepared and polymer (1b) was found to be useful for the protection of the hydroxy functional group; its use in the synthesis of an insect sex pheromone is reported.
SYNTHESIS OF DEC-5Z-ENYL ACETATE AND TETRADEC-9Z-ENYL ACETATE - COMPONENTS OF THE SEX PHEROMONE OF Agrotis segetum
Verba, G. G.,Bikulova, L. M.,Abduvakhabod, A. A.
, p. 130 - 131 (1988)
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SYNTHESIS OF PHEROMONE DERIVATIVES VIA Z-SELECTIVE OLEFIN METATHESIS
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Paragraph 0261-0262, (2021/12/28)
Disclosed herein are methods for synthesizing fatty olefin metathesis products of high Z-isomeric purity from olefin feedstocks of low Z-isomeric purity. The methods include contacting a contacting an olefin metathesis reaction partner, such as acylated alkenol or an alkenal acetal, with an internal olefin in the presence of a Z-selective metathesis catalyst to form the fatty olefin metathesis product. In various embodiments, the fatty olefin metathesis products are insect pheromones. Pheromone compositions and methods of using them are also described.
PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS
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, (2017/06/12)
In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R1 is independently selected from H, C1-18 alkyl, and C2-18 alkenyl; R2b is C1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.
