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169324-82-7

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169324-82-7 Usage

Description

2-(BOC-AMINO)-3-BUTEN-1-OL is a versatile chemical compound featuring a Boc (tert-butoxycarbonyl) protected amino group and a butenol moiety. This structure allows for selective reactions with other functional groups while preserving the amino functionality, making it a valuable building block in organic synthesis for creating complex molecules.

Uses

Used in Pharmaceutical Industry:
2-(BOC-AMINO)-3-BUTEN-1-OL is used as a synthetic intermediate for the development of bioactive compounds. Its Boc-protected amino group and butenol moiety enable the synthesis of various pharmaceutical agents with potential therapeutic applications.
Used in Agrochemical Industry:
In the agrochemical sector, 2-(BOC-AMINO)-3-BUTEN-1-OL serves as a key component in the synthesis of agrochemicals, such as pesticides and herbicides. Its reactivity and protective Boc group facilitate the creation of molecules with specific biological activities to control or eliminate unwanted plant species or pests.
Used in Materials Science:
2-(BOC-AMINO)-3-BUTEN-1-OL is utilized as a building block for the synthesis of polymers and other useful molecules in materials science. Its unique structure allows for the development of novel materials with tailored properties for various applications, such as coatings, adhesives, or advanced composites.

Check Digit Verification of cas no

The CAS Registry Mumber 169324-82-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,9,3,2 and 4 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 169324-82:
(8*1)+(7*6)+(6*9)+(5*3)+(4*2)+(3*4)+(2*8)+(1*2)=157
157 % 10 = 7
So 169324-82-7 is a valid CAS Registry Number.

169324-82-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl N-(1-hydroxybut-3-en-2-yl)carbamate

1.2 Other means of identification

Product number -
Other names 2-(boc-amino)-3-buten-1-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:169324-82-7 SDS

169324-82-7Relevant articles and documents

In situ enzymatic screening (ISES): A tool for catalyst discovery and reaction development

Berkowitz, David B.,Bose, Mohua,Choi, Sungjo

, p. 1603 - 1607 (2007/10/03)

Can enzymes help organic chemists identify new transition-metal catalysts? The first example of the in situ enzymatic monitoring of an organic transformation is described. Thus, a transition-metal-mediated allylic-amination reaction in the organic layer (

Fe(II)-catalyzed imidation of allyl sulfides and subsequent [2,3]- sigmatropic rearrangement. Preparation of α-branched N-tert-butyloxycarbonyl (Boc)-protected N-allylamines

Bach, Thorsten,Koerber, Christina

, p. 2358 - 2367 (2007/10/03)

Allyl aryl sulfides 1 and 5 were shown to undergo an imidation/[2,3]- sigmatropic rearrangement reaction upon treatment with N-tert- butyloxycarbonyl azide (BocN3) and catalytic amounts of FeCl2 in CH2Cl2. The N-Boc-protected N-allyl sulfenamides 3 and 21 were obtained in yields between 48 and 75% (12 examples). Whereas the reaction is well suited for the transformation of α-unbranched sulfides to α-branched sulfenamides, the enantiomerically pure α-branched sulfides 10 and 13 reacted sluggishly. The corresponding sulfenamides 22 and 23 were obtained in only moderate enantiomeric excess (36-39% ee). A reaction mechanism is proposed that postulates the intermediacy of an N-Boc-substituted Fe(IV)-nitrene complex 14 acting as the imidation reagent in the catalytic cycle. Possible side reactions are discussed. The benzenesulfenamides 3 were further converted into N-Boc-N-allylamines 4 by removal of the phenylsulfanyl group. Bu3SnH in benzene was found to be the reagent of choice for the deprotection of α- branched amines that bear a secondary allyl substituent (five examples, 71- 93% yield). This method failed for the α-branched amines 3i-k with a tertiary allyl substituent. The phenylsulfanyl group was finally removed with P(OEt)3/NEt3 in CH2Cl2 (three examples, 43-62% yield).

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