17375-29-0Relevant articles and documents
Manganese(II) carboxylates containing coordinated 3,5-dimethylpyrazole
Uvarova,Ageshina,Golubnichaya,Nefedov
, p. 934 - 941 (2015)
Reactions of manganese(II) pivalate, benzoate, and cymantrenecarboxylate with 3,5-dimethylpirazole (Hdmpz) have been found to result in mononuclear complexes (Hdmpz)4Mn(OOCR) where R = But and Ph, respectively, and binuclear complex {Mn(μ-OOCC5H4Mn(CO)3)(OOCC5H4Mn(CO)3) (Hdmpz)2(OH2)}2 which contains a pyrazole solvate molecule. The obtained complexes have been isolated in high yields as single crystals and have been characterized by chemical analysis, IR spectroscopy, and X-ray diffraction.
Efficient synthesis of manganese(ii) carboxylates: From a trinuclear cluster [Mn3(PhCO2)6(THF)4] to a unique [Mn(PhCO2)2]n chiral 3D network
Kornowicz, Arkadiusz,Komorski, Szymon,Wrobel, Zbigniew,Justyniak, Iwona,Nedelko, Natalia,Slawska-Waniewska, Anna,Balawender, Robert,Lewinski, Janusz
supporting information, p. 3048 - 3051 (2014/03/21)
An efficient synthetic procedure for obtaining manganese carboxylates including a trinuclear cluster [Mn3(PhCO2) 6(THF)4]2 and a unique [Mn(PhCO 2)2]n chiral 3D network is reported. The procedure involves a simple redox process, in which acidic protons are reduced to gaseous hydrogen by oxidizing metallic manganese under solvothermal conditions.
Manganese clusters derived from 2-pyridylcyanoxime: New topologies and a large spin ground state in pyridyloximate chemistry
Alcazar, Laura,Cordero, Beatriz,Esteban, Jordi,Tangoulis, Vassilis,Font-Bardia, Merce,Calvet, Teresa,Escuer, Albert
, p. 12334 - 12345 (2013/09/02)
Series of manganese clusters derived from 2-pyridylcyanoxime with Mn 3II (1), Mn4II (2a, b), Mn II4MnIII4 (3), MnII 2MnIII6MnIV2 (4) and MnII3MnIII6MnIV (5) cores have been characterized. Dc magnetic measurements reveal antiferromagnetic coupling for 1-4 and dominant ferromagnetic interactions for 5 which shows the largest ground state reported to date in pyridyloximate chemistry (S = 14).
