18819-89-1

• 

• Basic information

  1. Product Name: TETRABUTYLAMMONIUM BENZOATE
  2. Synonyms: Tetrabutylammonium benzoate puriss., electrochemical grade, >=99.0% (NT);TETRABUTYLAMMONIUM BENZOATE;tetrabutylammonium benzoate,electro-chemical grade;Tetrabutylammomium benzoate
  3. CAS NO:18819-89-1
  4. Molecular Formula: C₇H₅O₂*C₁₆H₃₆N
  5. Molecular Weight: 363.58
  6. EINECS: N/A
  7. Product Categories: Supporting Electrolytes for Electrochemistry;Ammonium;Ammonium Salts;Analytical Reagents;Analytical/Chromatography;Chemical Synthesis;Ionic Liquids;Phase Transfer Catalysts;Specialty Synthesis;Synthetic Reagents;Ammonium Salts;Ammonium SaltsAnalytical Reagents;AmmoniumGreener Alternatives: Catalysis;Chemical Synthesis;Electrochemistry;Ionic Liquids;Phase Transfer Catalysts;Supporting Electrolytes for Electrochemistry
  8. Mol File: 18819-89-1.mol
  9. Article Data: 20

• Chemical Properties

  1. Melting Point: 64-67 °C(lit.)
  2. Boiling Point: 425.5°C at 760 mmHg
  3. Flash Point: 148.7°C
  4. Appearance: /
  5. Density: 1.33g/cm³
  6. Vapor Pressure: 5.03E-09mmHg at 25°C
  7. Refractive Index: 1.491
  8. Storage Temp.: Inert atmosphere,Room Temperature
  9. Solubility: acetonitrile: 0.1 g/mL, clear, colorless
  10. BRN: 4070140
  11. CAS DataBase Reference: TETRABUTYLAMMONIUM BENZOATE(CAS DataBase Reference)
  12. NIST Chemistry Reference: TETRABUTYLAMMONIUM BENZOATE(18819-89-1)
  13. EPA Substance Registry System: TETRABUTYLAMMONIUM BENZOATE(18819-89-1)

• Safety Data

  1. Hazard Codes: Xi
  2. Statements: 36/37/38
  3. Safety Statements: 26-36
  4. WGK Germany: 3
  5. RTECS:
  6. F: 3-10
  7. HazardClass: N/A
  8. PackingGroup: N/A
  9. Hazardous Substances Data: 18819-89-1(Hazardous Substances Data)

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18819-89-1 Usage

General Description

Tetrabutylammonium benzoate is a chemical compound that is derived from benzoic acid and tetrabutylammonium, a quaternary ammonium salt. It is commonly used as a phase-transfer catalyst in various chemical reactions and organic synthesis processes. Tetrabutylammonium benzoate is a white, crystalline solid that is soluble in organic solvents and has a relatively low melting point. It is known for its ability to facilitate the transfer of reactants between immiscible phases, promoting the reaction between them. Additionally, it can also act as a surfactant and a stabilizer in certain systems. Overall, tetrabutylammonium benzoate plays a crucial role in the advancement of various chemical processes and industries.

Check Digit Verification of cas no

The CAS Registry Mumber 18819-89-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,8,8,1 and 9 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 18819-89:
(7*1)+(6*8)+(5*8)+(4*1)+(3*9)+(2*8)+(1*9)=151
151 % 10 = 1
So 18819-89-1 is a valid CAS Registry Number.

InChI:InChI=1/C14H20O10/c1-6(15)20-5-10-12(21-7(2)16)13(22-8(3)17)11(19)14(24-10)23-9(4)18/h10-14,19H,5H2,1-4H3/t10-,11+,12-,13-,14-/m1/s1

18819-89-1 Well-known Company Product Price

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• Sigma-Aldrich

• (86837)  Tetrabutylammoniumbenzoate  for electrochemical analysis, ≥99.0%

• 18819-89-1

• 86837-5G

• 1,112.67CNY

• Detail

• Sigma-Aldrich

• (86837)  Tetrabutylammoniumbenzoate  for electrochemical analysis, ≥99.0%

• 18819-89-1

• 86837-25G

• 4,440.15CNY

• Detail

18819-89-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name	tetrabutylazanium,benzoate

1.2 Other means of identification

Product number	-
Other names	tetra-n-butylammonium Benzoate

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:18819-89-1 SDS

18819-89-1Upstream product

• 429-42-5 tetrabutylammonium tetrafluoroborate 
• 532-31-0 silver benzoate 
• 311-28-4 tetra-(n-butyl)ammonium iodide 
• 3109-63-5 tert-butylammonium hexafluorophosphate(V) 
• 35895-70-6 tetrabutylammonium trifluoromethylsulfonate 

18819-89-1Downstream Products

• 31481-49-9 (1S,2S,5R)-1-benzoyl-2-(1-methylethyl)-5-methylcyclohexan-1-ol 
• 87007-63-4 N-menthyl-1,2-diethoxycarbonylhydrazine 
• 5342-31-4 bis(benzoyloxy)methane 
• 226226-37-5 C₂₆H₂₈O₉ 
• 429-42-5 tetrabutylammonium tetrafluoroborate 
• 183294-84-0 Cu(2,9-dimethyl-1,10-phenanthroline)2(benzoate) 

18819-89-1Relevant articles and documents

SN2 Reactions in Hydrocarbon Solvents Using Ammonium-Terminated Polyisobutylene Oligomers as Phase-Solubilizing Agents and Catalysts

Samunual, Peerada,Bergbreiter, David E.

, p. 11101 - 11107 (2018)

Although SN2 reactions have been thoroughly studied in polar aprotic and protic solvents, not many studies have been done to study the rate of SN2 reaction in nonpolar solvents like alkanes due to the insolubility of anionic nucleophiles in these solvents. In this study, we investigated the use of N,N-diethyl-N-methylammonium-terminated polyisobutylene oligomers as phase-solubilizing agents for nucleophilic anions that could react with hydrocarbon-soluble substrates in alkanes. The results of these kinetic studies showed alkanes were comparable to MeCN as solvents in many reactions. Based on these studies, we developed a solid/liquid catalytic process using insoluble alkali metal carboxylate salts and a recyclable soluble polyisobutylene-bound catalyst that can be used to carry out SN2 reactions both in heptane and in hydrocarbon oligomeric solvents known as poly(α-olefins) (PAOs).

Fluorescent Supramolecular Organic Frameworks Constructed by Amidinium-Carboxylate Salt Bridges

Jiang, Hongqin,Xie, Linhuang,Duan, Zhiming,Lin, Kunhua,He, Qing,Lynch, Vincent M.,Sessler, Jonathan L.,Wang, Hongyu

supporting information, p. 15006 - 15012 (2021/09/25)

We report here a set of fluorescent supramolecular organic frameworks (SOFs) that incorporate aggregation-induced emission (AIE) units within their frameworks. The fluorescent SOFs of this study were constructed by linking the tetraphenylethylene (TPE)-ba

Development and Elucidation of a Pd-Based Cyclization–Oxygenation Sequence for Natural Product Synthesis

Yi, Heng,Hu, Pengfei,Snyder, Scott A.

supporting information, p. 2674 - 2678 (2020/01/24)

Pd-catalyzed sequences involving oxidative addition, cyclization, and termination through intermolecular nucleophile capture have tremendous utility. Indeed, they can generate a plethora of different polycyclic structures possessing a diverse range of fun

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