195324-87-9

• 

• Basic information

  1. Product Name: 1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE
  2. Synonyms: 1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE
  3. CAS NO:195324-87-9
  4. Molecular Formula: C₁₄H₈BrF₁₃
  5. Molecular Weight: 503.1
  6. EINECS: N/A
  7. Product Categories: N/A
  8. Mol File: 195324-87-9.mol
  9. Article Data: 6

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: N/A
  3. Flash Point: N/A
  4. Appearance: /
  5. Density: N/A
  6. Refractive Index: N/A
  7. Storage Temp.: N/A
  8. Solubility: N/A
  9. CAS DataBase Reference: 1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE(CAS DataBase Reference)
  10. NIST Chemistry Reference: 1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE(195324-87-9)
  11. EPA Substance Registry System: 1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE(195324-87-9)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 195324-87-9(Hazardous Substances Data)

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• SDS
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• Downstream Products
• Article

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• 1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE

  Cas No: 195324-87-9

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• BOC Sciences
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• Benzene,1-bromo-4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)-

  Cas No: 195324-87-9

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• Fluorous Technologies Inc.
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195324-87-9 Usage

Common Uses

Production of surfactants, lubricants, and other industrial applications

Type of Compound

Perfluorinated compound

Definition of Perfluorinated

Contains fluorine atoms and has high thermal and chemical stability

Presence of Bromo Group

Useful for organic synthesis and as a building block for various other chemical compounds

Environmental Persistence

Highly fluorinated nature makes it persistent in the environment

Potential Toxic Effects

Can have toxic effects on living organisms

Regulatory Concerns

Restrictions on its use in some countries due to environmental and health concerns

Check Digit Verification of cas no

The CAS Registry Mumber 195324-87-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,9,5,3,2 and 4 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 195324-87:
(8*1)+(7*9)+(6*5)+(5*3)+(4*2)+(3*4)+(2*8)+(1*7)=159
159 % 10 = 9
So 195324-87-9 is a valid CAS Registry Number.

195324-87-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name	1-BROMO-4-(1H,1H,2H,2H-PERFLUOROOCTYL)BENZENE

1.2 Other means of identification

Product number	-
Other names	1-bromo-4-(2-perfluorohexyl)ethylbenzene

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:195324-87-9 SDS

195324-87-9Upstream product

• 25291-17-2 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene 
• 589-87-7 1,4-bromoiodobenzene 
• 340157-83-7 (E)-1-bromo-4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-octen-1-yl)benzene 
• 2043-57-4 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane 
• 106-37-6 1.4-dibromobenzene 

195324-87-9Downstream Products

• 290827-84-8 diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphine oxide 
• 356055-90-8 3-(naphthalen-2-ylsulfanyl)-butyric acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-benzyl ester 
• 356055-92-0 3-(4-tert-butyl-phenylsulfanyl)-butyric acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-benzyl ester 
• 356055-91-9 3-(4-methoxy-phenylsulfanyl)-butyric acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-benzyl ester 
• 356055-89-5 3-phenylsulfanyl-butyric acid 4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-octyl)-benzyl ester 
• 356055-79-3 4-(2-perfluorohexyl)ethylbenzyl crotonate 
• 356055-76-0 4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)benzyl alcohol 
• 219985-31-6 tris[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphane 
• 290827-93-9 diphenyl[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl]phosphane 
• 195324-94-8 bis<4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)phenyl>chlorophosphine 

195324-87-9Relevant articles and documents

Fluorous phosphines and phosphine oxides

-

, (2008/06/13)

A method of increasing the fluorous nature of a compound includes the step of reacting the compound with or tagging the compound with at least one of a second compound having the formula: wherein R is an alkyl group or an aryl group, n is 1, 2 or 3 and Rs is a spacer group and Rf is a branched fluorous group. A chemical compound having the general formula: wherein n, Rs and Rf are defined above.

A general method to fluorous ponytail-substituted aromatics

Chen, Weiping,Xu, Lijin,Xiao, Jianliang

, p. 4275 - 4278 (2007/10/03)

Palladium-catalyzed olefination of aryl halides led to a variety of fluorous ponytail-substituted, functionalized aryl compounds with good to excellent yields. The same chemistry was also applied to the synthesis of binaphathols bearing fluorinated ponytails.

Synthesis of perfluoroalkyl-substituted aryl bromides and their purification over fluorous reverse phase silica

Kainz, Sabine,Luo, Zhiyong,Curran, Dennis P.,Leitner, Walter

, p. 1425 - 1427 (2007/10/03)

(1H,1H,2H,2H-Perfluoroooctyl)-substituted aryl bromides 3a,b were synthesized via copper catalyzed cross-coupling of the iodide 1 with the corresponding arylmagnesium bromides 2a,b. A new, efficient method for the purification of highly fluorinated compounds by column chromatography on fluorous reverse phase silica is also described.

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