1001196-72-0

Basic information

• Product Name: [1-ethyl-3-methylimidazolium][Zn(1,3,5-benzenetricarboxylate)]
• Synonyms: [1-ethyl-3-methylimidazolium][Zn(1,3,5-benzenetricarboxylate)]
• CAS NO: 1001196-72-0
• Molecular Weight: 383.676
• Mol File: 1001196-72-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1-ethyl-3-methylimidazolium][Zn(1,3,5-benzenetricarboxylate)](CAS DataBase Reference)
• NIST Chemistry Reference: [1-ethyl-3-methylimidazolium][Zn(1,3,5-benzenetricarboxylate)](1001196-72-0)
• EPA Substance Registry System: [1-ethyl-3-methylimidazolium][Zn(1,3,5-benzenetricarboxylate)](1001196-72-0)

Safety Data

• Hazardous Substances Data: 1001196-72-0(Hazardous Substances Data)

Upstream product

• 554-95-0 benzene-1,3,5-tricarboxylic acid 
• 65039-08-9 3-ethyl-1-methyl-1H-imidazol-3-ium bromide 

Relevant articles and documents

Ionothermal syntheses of six three-dimensional zinc metal-organic frameworks with 1-alkyl-3-methylimidazolium bromide ionic liquids as solvents

We have performed ionothermal reactions between Zn(NO3) 2 and H3BTC in 1-alkyl-3-methylimidazolium bromide ionic liquids with the alkyl group varying from ethyl to amyl. Six 3-D metal-organic frameworks (MOFs), including two isomeric compounds [Zn3(BTC) 2(H2O)2]·2H2O (1 and 2) (H3BTC = 1,3,5-benzenetricarboxylate acid), [EMI]-[Zn(BTC)] (3) (E = ethyl, MI = 3-methylimidazolium), [PMI][Zn(BTC)](4) (P = propyl), [BMI] 2[Zn4(BTC)3(OH)-(H2O)3] (5) (B = butyl), and [AMI][Zn2(BTC)(OH)Br] (6) (A = amyl), have been synthesized and structurally characterized. Compounds 1 and 2 are isomeric compounds, in which the coordination modes of Zn atoms and the BTC3- ligands are considerably different. Compounds 3-6 crystallize with the corresponding ionic liquid cations incorporated in the frameworks. Their crystal structures show various features including various coordination geometries of Zn2+ and various bridging modes of the BTC3- ligands. The incorporated cations appear to have strong interactions with the frameworks.