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1005-61-4

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1005-61-4 Usage

General Description

1-Bromo-4-(ethenyloxy)benzene, also known as p-bromoallyloxybenzene, is a chemical compound with the molecular formula C8H7BrO. It is a white to off-white crystalline solid that is primarily used as an intermediate in the synthesis of pharmaceuticals and agrochemicals. 1-BroMo-4-(ethenyloxy)benzene is a derivative of bromobenzene and contains a benzene ring substituted with a bromine atom at the 1 position and an ethenyl group at the 4 position. It is commonly used for its reactivity in organic synthesis, particularly in the formation of carbon-carbon bonds in the production of various compounds. It is also used as a building block in the manufacture of dyes, perfumes, and flavorings. However, p-bromoallyloxybenzene is considered hazardous and should be handled with care due to its potential for causing irritation to the skin, eyes, and respiratory system.

Check Digit Verification of cas no

The CAS Registry Mumber 1005-61-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,0,0 and 5 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1005-61:
(6*1)+(5*0)+(4*0)+(3*5)+(2*6)+(1*1)=34
34 % 10 = 4
So 1005-61-4 is a valid CAS Registry Number.

1005-61-4Relevant articles and documents

Spin Delocalization, Polarization, and London Dispersion Forces Govern the Formation of Diradical Pimers

Ellern, Arkady,Peterson, Joshua P.,Winter, Arthur H.

, p. 5304 - 5313 (2020)

Some free radicals are stable enough to be isolated, but most are either unstable transient species or exist as metastable species in equilibrium with a dimeric form, usually a spin-paired sigma dimer or a pi dimer (pimer). To gain insight into the different modes of dimerization, we synthesized and evaluated a library of 15 aryl dicyanomethyl radicals in order to probe what structural and molecular parameters lead to σ- versus π-dimerization. We evaluated the divergent dimerization behavior by measuring the strength of each radical association by variableerature electron paramagnetic resonance spectroscopy, determining the mode of dimerization (σ- or π-dimer) by UV-vis spectroscopy and X-ray crystallography, and performing computational analysis. We evaluated three different hypotheses to explain the difference in the dimerization behavior: (1) that the dimerization behavior is dictated by radical spin densities; (2) that it is dictated by radical polarizability; (3) that it is dictated by London dispersion stabilization of the pimer. However, no single parameter model in itself was predictive. Two-parameter models incorporating either the computed degree of spin delocalization or the radical polarizability as well as computed estimates for the attractive London dispersion forces in the π-dimers lead to improved forecasts of σ- vs π-dimerization mode, and suggest that a balance of spin delocalization of the isolated radical as well as attractive forces between the stacked radicals, govern the formation of diradical pimers.

HYDROXY ISOXAZOLE COMPOUNDS USEFUL AS GPR120 AGONISTS

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Page/Page column 50, (2018/07/05)

The present invention relates to a compound represented by formula (I) : and pharmaceutically acceptable salts thereof are disclosed as useful for treating or preventing diabetes, hyperlipidemia, obesity, NASH, inflammation related disorders, and related diseases and conditions. The compounds are useful as agonists of the G-protein coupled receptor GPR120. Pharmaceutical compositions and methods of treatment are also included.

Bis(aryl)acetal compounds

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Page/Page column 31-32, (2015/02/19)

A bis(aryl)acetal has the formula wherein Y1 and Y2 are each independently chloro, bromo, iodo, mesylate, tosylate, triflate, or Bx, provided that Y1 and Y2 are not both selected from chloro, bromo, a

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