1007881-56-2Relevant articles and documents
Synthesis and reactions of organic compounds with a nitrogen atom. Part XV. Reactions of (+)-3-chloro-2(10)-pinene and (-)-10-chloro-2-pinene with phenyltelluro- and phenylselenosodium
Uzarewicz,Scianowski,Bakowska-Janiszewska
, p. 1791 - 1796 (2007/10/03)
Toluenesulfonamidation of (+)-3-chloro-2(10)-pinene (4) and (-)-10-chloro-2-pinene (5) with phenylselenosodium (2) or phenyltellurosodium (3) and chloramine-T gave exclusively N-trans-[2′(10′) pinen-3′-yl]toluenesulfonamide (7). Oxidation of 10-phenylseleno-2-pinene (6) and 10-phenyltelluro-2-pinene (12) prepared from the chlorides 4 and 5 was examined. The reduction of toluenesulfonamide 7 with sodium in liquid ammonia gave (+)-trans-3-amino-2(10)-pinene (8).