101-34-8

Basic information

• Product Name: GLYCEROL TRIACETYLRICINOLEATE
• Synonyms: 1,2,3-propanetriyl;9-octadecenoicacid,12-(acetyloxy)-,1,2,3-propanetriylester,stereoisomer;GLYCERYL TRI-(ACETYL RICINOLEATE);GLYCEROL TRIACETYLRICINOLEATE;12-(ACETYLOXY)-9-OCTADECENOIC ACID-(9Z, 9'Z, 9''Z, 12R, 12'R,12''R)-1,2,3-PROPANETRIYL ESTER;1,2,3-propanetriyl tris[(R)-12-(acetoxy)oleate];PLASTICIZER A-100D;Glycerol, tris(12-acetoxyoleate)
• CAS NO: 101-34-8
• Molecular Formula: C₆₃H₁₁₀O₁₂
• Molecular Weight: 1059.54
• EINECS: 202-935-1
• Mol File: 101-34-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 904.9°Cat760mmHg
• Flash Point: 325.7°C
• Appearance: /
• Density: 0.988g/cm³
• Vapor Pressure: 1.51E-33mmHg at 25°C
• Refractive Index: 1.48
• CAS DataBase Reference: GLYCEROL TRIACETYLRICINOLEATE(CAS DataBase Reference)
• NIST Chemistry Reference: GLYCEROL TRIACETYLRICINOLEATE(101-34-8)
• EPA Substance Registry System: GLYCEROL TRIACETYLRICINOLEATE(101-34-8)

Safety Data

• Hazardous Substances Data: 101-34-8(Hazardous Substances Data)

Usage

Uses

Glyceryl Triacetoricinoleate is a potential lubricant base stock based upon castor oil.

Flammability and Explosibility

Notclassified

InChI:InChI=1/C63H110O12/c1-7-10-13-34-43-57(72-54(4)64)46-37-28-22-16-19-25-31-40-49-61(67)70-52-60(75-63(69)51-42-33-27-21-18-24-30-39-48-59(74-56(6)66)45-36-15-12-9-3)53-71-62(68)50-41-32-26-20-17-23-29-38-47-58(73-55(5)65)44-35-14-11-8-2/h28-30,37-39,57-60H,7-27,31-36,40-53H2,1-6H3/b37-28-,38-29-,39-30-/t57-,58-,59-/m1/s1

Upstream product

• 108-24-7 acetic anhydride 
• 15505-14-3 castor oil 
• 56-81-5 glycerol 

Downstream Products

• 939772-34-6 C₃₀H₅₆O₉ 
• 121541-65-9 (R)-(-)-1,3-nonandiol 1 
• 7779-54-6 1-acetoxy-3-nonanone 
• 1732-10-1 Dimethyl azelate 
• 38044-20-1 8-cyanooctanoic acid methyl ester 
• 28941-56-2 methyl ester of (R)-3-hydroxynonanoic acid 

Relevant articles and documents

Synthesis and properties of castor oil based plasticizers

A series of environment-friendly plasticizers has been synthesized from castor oil through a mild esterification/epoxidation reaction. The modified epoxy acetylated castor oil (EACO) can plastify poly(vinyl chloride) (PVC) efficiently, even better than the commercial plasticizers dioctyl terephthalate (DOTP) and epoxidized soybean oil (ESO), in terms of in tensile strength, migration stability, solvent extraction stability and thermal stability. Specifically, the tensile strength and elongation at break of a PVC sample plastified by epoxy acetylated castor oil (EACO) were 18.5 and 10.0% higher than that of DOTP, and 13.9 and 23.8% higher than that of ESO, respectively. Volatility, migration, solvent extraction and thermal stability tests indicated that the presence of carbon-carbon double bonds and hydroxy groups reduce the compatibility of a plasticizer with PVC while the presence of epoxy groups and ester bonds can improve the plasticizing effect of the plasticizer on PVC. In addition, alkyl groups can improve the plasticizing effect on PVC while benzene rings increase the rigidity of the PVC. The design strategy based on castor oil highlights a sustainable avenue for preparing cost-effective and high-efficiency plasticizers.