101025-08-5

Basic information

• Product Name: 1-BROMO-11-PHENYL UNDECANE
• Synonyms: 1-BROMO-11-PHENYL UNDECANE;RARECHEM AH CK 0051;1-BROMO-11-PHENYL-UNDECANE >97%
• CAS NO: 101025-08-5
• Molecular Formula: C₁₇H₂₇Br
• Molecular Weight: 311.3
• Mol File: 101025-08-5.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 369.5 °C at 760 mmHg
• Flash Point: 179.1 °C
• Appearance: /
• Density: 1.096 g/cm³
• Vapor Pressure: 2.51E-05mmHg at 25°C
• Refractive Index: 1.512
• CAS DataBase Reference: 1-BROMO-11-PHENYL UNDECANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BROMO-11-PHENYL UNDECANE(101025-08-5)
• EPA Substance Registry System: 1-BROMO-11-PHENYL UNDECANE(101025-08-5)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 101025-08-5(Hazardous Substances Data)

Usage

General Description

1-Bromo-11-phenyl undecane is a long-chain alkyl bromide compound with the chemical formula C16H25Br. It is a colorless to pale yellow liquid with a boiling point of 301°C. This chemical is commonly used as an intermediate for the synthesis of various organic compounds and pharmaceuticals. It is also used in organic synthesis and as a reagent in chemical reactions. 1-Bromo-11-phenyl undecane is a flammable liquid and should be handled with caution due to its potential hazards.

InChI:InChI=1/C17H27Br/c18-16-12-7-5-3-1-2-4-6-9-13-17-14-10-8-11-15-17/h8,10-11,14-15H,1-7,9,12-13,16H2

Upstream product

• 947611-27-0 C₂₂H₃₆O₂ 
• 52056-69-6 2-[(11-bromoundecyl)oxy]tetrahydro-2H-pyran 
• 1611-56-9 1-Bromo-11-hydroxyundecane 
• 107224-27-1 1-Phenyl-1-undecene 
• 116408-91-4 5-benzylthiophen-2-hexanoic acid 
• 13132-15-5 2-benzylthiophene 
• 3343-24-6 ω-phenyl undecanoic acid 
• 1071-71-2 ethyl 6-chloro-6-oxohexanoate 
• 16696-65-4 1,11-dibromoundecane 
• 591-51-5 phenyllithium 
• 61439-50-7 11-phenylundecylalcohol 
• 100-52-7 benzaldehyde 
• 17049-50-2 n-decyl magnesium bromide 
• 6990-68-7 1-phenylundecan-1-ol 

Downstream Products

• 61439-52-9 p-[(11-phenylundecyl)amino]benzoic acid 
• 608881-75-0 [4-(11-acetylsulfanylundecyl)phenyl](2-methylphenyl)methanone 
• 116385-00-3 triphenyl(11-phenylundecyl)phosphonium bromide 
• 14401-84-4 1,14-Diphenyl-tetradecadien-(1,3) 

Relevant articles and documents

Air-Stable PdI Dimer Enabled Remote Functionalization: Access to Fluorinated 1,1-Diaryl Alkanes with Unprecedented Speed

While remote functionalization via chain walking has the potential to enable access to molecules via novel disconnections, such processes require relatively long reaction times and can be in need of elevated temperatures. This work features a remote arylation in less than 10 min reaction time at room temperature over a distance of up to 11 carbons. The unprecedented speed is enabled by the air-stable PdI dimer [Pd(μ-I)(PCy2tBu)]2, which in contrast to its PtBu3 counterpart does not trigger direct coupling at the initiation site, but regioconvergent and chemoselective remote functionalization to yield valuable fluorinated 1,1-diaryl alkanes. Our combined experimental and computational studies rationalize the origins of switchability, which are primarily due to differences in dispersion interactions.

Synthesis and Identification of ω-Phenylalkylcatechols in Burmese Lac

The presence of 3-(10'-phenyldecyl)- (2) (2percent), 3-(12'-phenyldodecyl)- (3) (6percent), 4-(10'-phenyldecyl)- (4) (0.3percent) and 4-(12'-phenyldodecyl)-benzene-1,2-diol (5) (0.3percent) in Burmese lac, the sap of Melanorrhoea usitata Wall has been confirmed by the synthesis of these compounds and a comparison of the gas chromatographic retention times and the mass spectral characteristic of their bis-O-(trimethylsilyl) derivatives with the derivatives of the natural products.Typically, 3,4-bis(benzyloxy)benzaldehyde (7) on Wittig reaction with triphenyl(11-phenylundecyl)phosphonium bromide (20) and subsequent catalytic hydrogenation of the resultant olefin gave compound (5) in 59percent overall yield.