101068-99-9

Basic information

• Product Name: methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside
• Synonyms: methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside
• CAS NO: 101068-99-9
• Molecular Weight: 490.51
• Mol File: 101068-99-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside(101068-99-9)
• EPA Substance Registry System: methyl 2,3,4-tri-O-benzoyl α-L-rhamnopyranoside(101068-99-9)

Safety Data

• Hazardous Substances Data: 101068-99-9(Hazardous Substances Data)

Upstream product

• 1128-40-1 methyl L-rhamnopyranoside 
• 98-88-4 benzoyl chloride 
• 67-56-1 methanol 
• 14218-08-7 2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl bromide 
• 69557-83-1 methyl-4-O-benzoyl-α-L-rhamnopyranoside 
• 14917-55-6 methyl 6-deoxy-α-L-mannopyranoside 
• 7512-03-0 methyl 2,3,4-tri-O-benzoyl-6-deoxy-α-D-mannopyranoside 
• 6155-35-7 L-rhamnose monohydrate 
• 61198-83-2 1,2,3,4-tetra-O-benzoyl-6-desoxy-α-L-mannopyranose 
• 6014-42-2 L-rhamnose 
• 14133-63-2 methyl 2,3-O-isopropylidene-α-L-rhamnoside 
• 101068-96-6 Benzoic acid (2S,3S,4R,5R,6R)-4,5-diacetoxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 52681-72-8 methyl-4-O-benzoyl-2,3-O-isopropylidene-α-L-rhamnopyranoside 

Downstream Products

• 7512-03-0 methyl-(tri-O-benzoyl-α-DL-rhamnopyranoside) 
• 146934-34-1 2,3,4-Tri-O-benzoyl-α-L-rhamnopyranosyl chloride 
• 146934-40-9 1-(Trimethylsilyl)ethyl 2,4-di-O-benzoyl-3-O-(2,4-di-O-benzoyl-3-O-chloroacetyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside 
• 146934-41-0 1-(Trimethylsilyl)ethyl 2,4-di-O-benzoyl-3-O-(2,4-di-O-benzoyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranoside 
• 146934-35-2 2-(Trimethylsilyl)ethyl 2,3,4-tri-O-benzoyl-α-L-rhamnopyranoside 
• 146934-37-4 2-(Trimethylsilyl)ethyl 2,4-di-O-benzoyl-α-L-rhamnopyranoside 
• 141020-07-7 C₂₉H₂₆O₉ 

Relevant articles and documents

Glycolipids from Sponges. 13. Clarhamnoside, the First Rhamnosylated α-Galactosylceramide from Agelas clathrodes. Improving Spectral Strategies for Glycoconjugate Structure Determination

Reinvestigation of the glycosphingolipid composition of the marine sponge Agelas clathrodes revealed the presence of a new tetraglycosylated α-galactoglycosphingolipid (1a), containing an unusual L-rhamnose unit in the sugar head. The structure of the new compound was elucidated using extensive 2D NMR studies. Because of the strong overlapping of the signals of the sugar protons in the 1H spectrum, 13C-coupled and 13C-decoupled phase-sensitive HMQC spectra were used to study the multiplicity of the overlapping signals. In addition, the absolute configuration of sugars was determined using a simple and efficient, yet underutilized CD method.

SYNTHESIS OF THE O-SPECIFIC POLYSACCHARIDE OF SHIGELLA FLEXNERI

A regular heteropolysaccharide built of tetrasaccharide repeating units is synthesised by means of regio- and stereospecific polycondensation of tritylated cyanoethylidene derivative.The polysaccharide obtained is identical with the O-antigenic polysaccharides of Shigella flexneri serotypes 3b, 3c, and variant Y.It also represents the basic chain of O-antigenic polysaccharides of all serotypes of this bacterium.