10122-97-1

Basic information

• Product Name: diphenylphosphonic acid propyl ester
• Synonyms: diphenylphosphonic acid propyl ester
• CAS NO: 10122-97-1
• Molecular Weight: 260.273
• Mol File: 10122-97-1.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: diphenylphosphonic acid propyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: diphenylphosphonic acid propyl ester(10122-97-1)
• EPA Substance Registry System: diphenylphosphonic acid propyl ester(10122-97-1)

Safety Data

• Hazardous Substances Data: 10122-97-1(Hazardous Substances Data)

Upstream product

• 92556-46-2 diphenyl n-propoxyphosphine 
• 71-23-8 propan-1-ol 
• 1706-90-7 methyl diphenylphosphinate 
• 4559-70-0 Diphenylphosphine oxide 
• 1707-03-5 diphenyl-phosphinic acid 
• 1779-48-2 phenylphosphinic acid 
• 108-86-1 bromobenzene 
• 6911-99-5 n-propyl phenyl-H-phosphinate 
• 106-94-5 propyl bromide 
• 1499-21-4 Diphenylphosphinic chloride 
• 4403-51-4 bis(diethylphosphoryl)disulfide 

Downstream Products

• 1707-03-5 diphenyl-phosphinic acid 

Relevant articles and documents

Hydrolysis and alcoholysis of phosphinates and phosphonates

Phosphinic and phosphonic acids useful intermediates and biologically active compounds may be prepared from their esters: phosphinates and phosphonates, respectively, by acid-catalyzed hydrolysis either on conventional heating or on MW irradiation. The transesterification of alkyl phosphinates took place only in the presence of suitable ionic liquids as the catalysts. In the cases of phenylphosphonates, depending on the nature of the ionic liquid, the formation of the ester was accompanied by the fission of the C–O bond.

A phosphoryl radical-initiated Atherton-Todd-type reaction under open air

A phosphoryl radical-initiated Atherton-Todd-type reaction using air as the radical initiator and CHCl3 as the halogenating reagent for the phosphorylation of alcohols, phenols, and amines has been developed. This novel transformation provides a highly efficient route to important phosphinates, phosphinic amides, and phosphoramidates in up to 99% yield with a broad substrate scope under very mild conditions (48 examples).

Electrochemical Dehydrogenative Coupling of Alcohols with Hydrogen Phosphoryl Compounds: A Green Protocol for P?O Bond Formation

This study reports the environment-friendly electrochemical transformation of structurally diverse phosphorus compounds and alcohol into phosphonates in the presence of ammonium iodide as electrolyte and redox catalyst in acetonitrile at ambient temperature. This method for P?O bond formation exhibits remarkable features, such as transition metal- and oxidant-free conditions. A reliable mechanism is proposed after control and cyclic voltammetry experiments. (Figure presented.).