101315-21-3

Basic information

• Product Name: 4-Penten-2-yn-1-ol, 5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-
• CAS NO: 101315-21-3
• Molecular Formula: C14H20O
• Molecular Weight: 204.312
• Mol File: 101315-21-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-Penten-2-yn-1-ol, 5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Penten-2-yn-1-ol, 5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-(101315-21-3)
• EPA Substance Registry System: 4-Penten-2-yn-1-ol, 5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-(101315-21-3)

Safety Data

• Hazardous Substances Data: 101315-21-3(Hazardous Substances Data)

Upstream product

• 475673-41-7 (E)-2-(2,6,6-trimethylcyclohexen-1-yl)ethenyl nonafluorobutanesulfonate 
• 303779-99-9 (E)-2-(2,6,6-trimethylcyclohexen-1-yl)-ethenyl (trifluoromethyl)sulfonate 
• 472-66-2 (2,6,6-trimethyl-1-cyclohexen-1-yl)acetaldehyde 
• 107-19-7 propargyl alcohol 
• 50-00-0 formaldehyd 
• 79-77-6 (E)-β-ionone 
• 73395-75-2 (E)-2-(but-1-en-3-ynyl)-1,3,3-trimethylcyclohex-1-ene 

Downstream Products

• 111917-85-2 (2E,4E)-3-Azido-5-(2,6,6-trimethyl-cyclohex-1-enyl)-penta-2,4-dienal 
• 111943-10-3 3-[(E)-2-(2,6,6-Trimethyl-cyclohex-1-enyl)-vinyl]-2H-azirine-2-carbaldehyde 
• 101315-18-8 all-trans-9,10-Didehydro-19-norretinal 
• 101347-23-3 (2Z,4E,8E)-3-methyl-9-(2',6',6'-trimethylcyclohex-1-enyl)nona-2,4,8-trien-6-ynal 
• 109051-58-3 9,10-Didehydro-19-norretinsaeurenitril 
• 223419-01-0 methyl (E,E)-4-hydroxy-2-<2-(2,6,6-trimethylcyclohex-1-enyl)vinyl>but-2-enoate 
• 128293-12-9 methyl (E,E)-4-oxo-2-<2-(2,6,6-trimethylcyclohex-1-enyl)vinyl>but-2-enoate 
• 204063-23-0 (E,E)-4-hydroxy-2-<2-(2,6,6-trimethylcyclohex-1-enyl)vinyl>but-2-enoic acid 
• 101315-22-4 5-(2',6',6'-trimethyl-1'-cyclohexen-1'-yl)-4-penten-2-yn-1-al 

Relevant articles and documents

Palladium-catalyzed coupling reaction of an enol nonaflate with (vinyl)tributylstannanes and acetylenes: A highly stereoselective synthesis of 8,18-13C2-labeled retinal

Here we report that enol nonaflates exhibit higher reactivity than the corresponding enol triflates in palladium-catalyzed cross-coupling reactions with various (vinyl)tributylstannanes and acetylenes. We also highlight the reaction of a vinyl nonaflate,

The inhibitory mechanism of bovine pancreatic phospholipase A2 by aldehyde terpenoids

We established the stereoselective synthesis of (E)-3-methoxycarbonyl- 2,4,6-trienal compound A and discovered that the compound A showed more powerful inhibitory activity toward phospholipase A2(PLA2) from bovine pancreas than manoalide which is a typical PLA2 inhibitor. As the inhibitory mechanism of PLA2 by A, the irreversible formation of dihydropyridine derivative resulting from the reaction of A with lysine residues in PLA2 was proposed based on the model reactions. Furthermore, A was found to selectively modify Lys56 which is included in the interfacial recognition site of this enzyme by the MALDI-TOF-MS peptide mapping analyses.

Synthesis of the acetylenic retinoids 9,10-didehydro-19-norretinal and 9,10,11,12-tetradehydro-19-norretinal

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