1013652-06-6

Basic information

• Product Name: (2R,4R,6S,7R)-7-benzyloxy-2-(tert-butyldiphenylsilyloxy)-4,6-dimethylnonan-4-ol
• Synonyms: (2R,4R,6S,7R)-7-benzyloxy-2-(tert-butyldiphenylsilyloxy)-4,6-dimethylnonan-4-ol
• CAS NO: 1013652-06-6
• Molecular Weight: 532.839
• Mol File: 1013652-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4R,6S,7R)-7-benzyloxy-2-(tert-butyldiphenylsilyloxy)-4,6-dimethylnonan-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4R,6S,7R)-7-benzyloxy-2-(tert-butyldiphenylsilyloxy)-4,6-dimethylnonan-4-ol(1013652-06-6)
• EPA Substance Registry System: (2R,4R,6S,7R)-7-benzyloxy-2-(tert-butyldiphenylsilyloxy)-4,6-dimethylnonan-4-ol(1013652-06-6)

Safety Data

• Hazardous Substances Data: 1013652-06-6(Hazardous Substances Data)

Upstream product

• 1013652-05-5 (2R,6S,7R)-7-benzyloxy-2-(tert-butyldiphenylsilyloxy)-6-methylnonan-4-one 
• 74-88-4 methyl iodide 

Downstream Products

• 1013652-07-7 (2R,4R,6S,7R)-7-(benzyloxy)-4,6-dimethylnonane-2,4-diol 

Relevant articles and documents

Stereoselective synthesis of (+)-sordidin, the male-produced aggregation pheromone of the banana weevil Cosmopolites sordidus

Stereoselective synthesis of (1S,3R,5R,7S)-(+)-sordidin, the natural male-produced aggregation pheromone of the banana weevil Cosmopolites sordidus (Germar) starting from 5-benzyloxy-(2E)-pentene-1-ol is described. The key transformations employed in the synthesis are Sharpless asymmetric epoxidation, Ueno-Stork cyclization, and Jacobsen kinetic resolution.