101499-38-1

Basic information

• Product Name: dimethyl 2,2-dimethyl-3-phenylpentane-1,5-dioate
• Synonyms: dimethyl 2,2-dimethyl-3-phenylpentane-1,5-dioate
• CAS NO: 101499-38-1
• Molecular Weight: 264.321
• Mol File: 101499-38-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: dimethyl 2,2-dimethyl-3-phenylpentane-1,5-dioate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2,2-dimethyl-3-phenylpentane-1,5-dioate(101499-38-1)
• EPA Substance Registry System: dimethyl 2,2-dimethyl-3-phenylpentane-1,5-dioate(101499-38-1)

Safety Data

• Hazardous Substances Data: 101499-38-1(Hazardous Substances Data)

Upstream product

• 31469-15-5 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene 
• 103-26-4 Methyl cinnamate 
• 868070-20-6 triisopropyl((1-methoxy-2-methylprop-1-en-1-yl)oxy)silane 
• 78-79-5 isoprene 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 103-26-4 methyl cinnamate 
• 186581-53-3 diazomethane 

Downstream Products

• 1242096-20-3 dimethyl 2,2,6,6-tetramethyl-3-oxo-5-phenyl-1,7-heptanedioate 
• 1242096-21-4 dimethyl 2-ethyl-2,6,6-trimethyl-3-oxo-5-phenyl-1,7-heptanedioate 
• 1242096-22-5 1-tert-butyl 7-methyl 2,2,6,6-tetramethyl-3-oxo-5-phenyl-1,7-heptadioate 
• 100972-49-4 2,2-dimethyl-3-phenyl-glutaric acid-1-methyl ester 

Relevant articles and documents

Photoaddition of ketene silyl acetals to electron-deficient arylakenes via single electron transfer

Photoreaction of 1-cyano-2-phenylethene and 1,1-dicyano-2-phenylethene with β,β-dialkyl-substituted ketene silyl acetals in acetonitrile in the presence of aromatic hydrocarbon as a photosensitizer regioselectively afforded alkylated products in high yields.

Scalable and Highly Diastereo- and Enantioselective Catalytic Diels-Alder Reaction of α,β-Unsaturated Methyl Esters

Despite tremendous advances in enantioselective catalysis of the Diels-Alder reaction, the use of simple α,β-unsaturated esters, one of the most abundant and useful class of dienophiles, is still severely limited in scope due to their low reactivity. We report here a catalytic asymmetric Diels-Alder methodology for a large variety of α,β-unsaturated methyl esters and different dienes based on extremely reactive silylium imidodiphosphorimidate (IDPi) Lewis acids. Mechanistic insights from accurate domain-based local pair natural orbital coupled-cluster (DLPNO-CCSD(T)) calculations rationalize the catalyst control and stereochemical outcome.

First sequential Mukaiyama-Michael reaction/crossed-Claisen condensation using two molar ketene silyl acetals and one molar α,β-unsaturated esters promoted by a NaOH catalyst

The NaOH-catalyzed first sequential Mukaiyama-Michael reaction/crossed- Claisen condensation is developed using two molar ketene silyl acetals and one molar α,β-unsaturated esters in either a stepwise or one-pot manner.