101600-65-1

Basic information

• Product Name: (6-methoxyquinolin-2-yl)(phenyl)methanone
• Synonyms: (6-methoxyquinolin-2-yl)(phenyl)methanone
• CAS NO: 101600-65-1
• Molecular Weight: 263.296
• Mol File: 101600-65-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (6-methoxyquinolin-2-yl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (6-methoxyquinolin-2-yl)(phenyl)methanone(101600-65-1)
• EPA Substance Registry System: (6-methoxyquinolin-2-yl)(phenyl)methanone(101600-65-1)

Safety Data

• Hazardous Substances Data: 101600-65-1(Hazardous Substances Data)

Upstream product

• 40018-26-6 1,4-dithiane-2,5-diol 
• 104-94-9 4-methoxy-aniline 
• 98-86-2 acetophenone 
• 113628-33-4 2-(4-methoxyphenylimino)-1-phenylethanone 
• 1401615-84-6 (1-(4-methoxyphenylamino)cyclopropyl)(phenyl)methanone 
• 5883-82-9 2-((4-methoxyphenyl)amino)-1-phenylethanone 
• 6334-31-2 1-benzoyl-6-methoxy-1,2-dihydro-quinoline-2-carbonitrile 

Relevant articles and documents

I2-Promoted Povarov-Type Reaction Using 1,4-Dithane-2,5-diol as an Ethylene Surrogate: Formal [4 + 2] Synthesis of Quinolines

A highly efficient I2-promoted formal [4 + 2] cycloaddition has been developed for the synthesis of 2-acylquinolines from methyl ketones and arylamines using 1,4-dithane-2,5-diol as an ethylene surrogate. Moreover, the investigation of the mechanism suggested that this reaction occurred via an iodination/Kornblum oxidation/Povarov/aromatization sequence. It is noteworthy that the arylamine substrate also played an important role in promoting the reaction.