101614-59-9

Basic information

• Product Name: N,N-diisopropyl-4-vinylbenzamide
• Synonyms: N,N-diisopropyl-4-vinylbenzamide
• CAS NO: 101614-59-9
• Molecular Weight: 231.338
• Mol File: 101614-59-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N,N-diisopropyl-4-vinylbenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diisopropyl-4-vinylbenzamide(101614-59-9)
• EPA Substance Registry System: N,N-diisopropyl-4-vinylbenzamide(101614-59-9)

Safety Data

• Hazardous Substances Data: 101614-59-9(Hazardous Substances Data)

Upstream product

• 1565-41-9 p-vinylbenzoyl chloride 
• 108-18-9 diisopropylamine 
• 1076-96-6 methyl 4-vinylbenzoate 
• 1075-49-6 4-ethenylbenzoic acid 

Relevant articles and documents

Direct Hydroxylation and Amination of Arenes via Deprotonative Cupration

Deprotonative directed ortho cupration of aromatic/heteroaromatic C-H bond and subsequent oxidation with t-BuOOH furnished functionalized phenols in high yields with high regio- and chemoselectivity. DFT calculations revealed that this hydroxylation reaction proceeds via a copper (I → III → I) redox mechanism. Application of this reaction to aromatic C-H amination using BnONH2 efficiently afforded the corresponding primary anilines. These reactions show broad scope and good functional group compatibility. Catalytic versions of these transformations are also demonstrated.