101664-64-6Relevant articles and documents
A general synthesis of (±)-dibenzocyclooctadiene lignans
Takeya, Tetsuya,Yamaki, Shinobu,Itoh, Toshimasa,Hosogai, Hiroko,Tobinaga, Seisho
, p. 909 - 918 (2007/10/03)
We have established a new general synthesis for (±)- dibenzocyclooctadiene lignans, including (±)-schizandrin (1a), (±)-gomisin A (1b), (±)-isoschizandrin (3a), and (±)-isogomisin A (3b), via the spiro- dienone ethers E- and T-11 as the key intermediates, prepared from the corresponding bisarylbutanol derivatives E- and T-10 by the oxidation with Weitz' aminium salt, tris(4-bromophenyl)aminium hexachloroantimonate (BAHA). These syntheses consist of 13 steps from the phenylpropanone 5.
A practical synthesis of d,l-dibenzocyclooctadiene lignans, d,l-deoxyschizandrin, d,l-wuweizisu C, and their stereoisomers
Takeya,Okubo,Nishida,Tobinaga
, p. 3599 - 3607 (2007/10/02)
-