101711-90-4Relevant articles and documents
Syntheses of all the stereoisomers of butanol type 1,7-seco-2,7′-cyclolignane
Yamauchi, Satoshi,Tomiyama, Chisato,Wukirsari, Tuti,Nishiwaki, Hisashi
, p. 19 - 28 (2014)
All the stereoisomers of butanol type 1,7-seco-2,7′-cyclolignane were stereoselectively synthesized by employing (S)- and (R)-Evans' auxiliaries to construct the stereochemistry. (+)- and (-)-Kadangustin J and their diastereomers were also prepared. The optical purity of the synthesized butanol type 1,7-seco-2,7′-cyclolignane was more than 99%ee.
Asymmetric synthesis of (E)-dehydroapratoxin A
Ma, Jing-Yi,Huang, Wei,Wei, Bang-Guo
scheme or table, p. 4598 - 4601 (2011/09/30)
An asymmetric approach to key intermediate 17 starting from lactone 7 is described, in which Evan's alkylation and CBS-catalyzed reduction are used for construction of the chiral centers, respectively. Thus, the synthesis of (E)-dehydroapratoxin A 6 could
N-FORMYL HYDROXYLAMINE COMPOUNDS
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Page/Page column 18-19, (2008/06/13)
Novel N-formyl hydroxylamine compounds and their derivatives are disclosed. These N-formyl hydroxylamine compounds inhibit peptidyl deformylase (PDF), an enzyme present in prokaryotes. The compounds are useful as antimicrobials and antibiotics. The compou