102061-00-7

Basic information

• Product Name: N-phenylacetyl-L-proplinol
• Synonyms: N-phenylacetyl-L-proplinol
• CAS NO: 102061-00-7
• Molecular Weight: 219.283
• Mol File: 102061-00-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-phenylacetyl-L-proplinol(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenylacetyl-L-proplinol(102061-00-7)
• EPA Substance Registry System: N-phenylacetyl-L-proplinol(102061-00-7)

Safety Data

• Hazardous Substances Data: 102061-00-7(Hazardous Substances Data)

Upstream product

• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 
• 101-41-7 benzeneacetic acid methyl ester 
• 103-80-0 phenylacetyl chloride 
• 1555-80-2 phenylacetic anhydride 

Downstream Products

• 102061-04-1 (2S)-2-(hydroxymethyl)-1-[(2R)-2-hydroxy-2-phenylacetyl]pyrrolidine 
• 102061-02-9 (S)-2-hydroxymethyl-N-((R)-2-hydroxy-2-phenyl)-acetyl pyrrolidine 

Relevant articles and documents

N-heterocyclic carbene-catalyzed amidation of unactivated esters with amino alcohols

(Chemical Equation Presented) A catalytic amidation of unactivated esters with amino alcohols is described. A series of solution studies in addition to the first X-ray structure of a carbene-alcohol complex support a carbene-base nucleophile activation mechanism.

ASYMMETRIC SYNTHESIS OF α-HYDROXY CARBOXYLIC ACIDS: DIRECT OXIDATION OF CHIRAL AMIDE ENOLATES USING 2-SULFONYLOXAZIRIDINES

The direct oxidation of chiral amide enolates to optically active mandelic acid using 2-sulfonyloxaziridine 1 is described.The diastereoselectivity is counterion dependent.